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      A solvato-fluorochromic macrocycle of multiple anthracene fluorophores in close proximity.

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          Abstract

          A fluorescent macrocycle containing four anthracene panels linked by meta-phenylene spacers and amino hinges was synthesized. The macrocycle adopts a twisted, compressed conformation that places embedded anthracene fluorophores in close contact. Emission from the convoluted macrocycle is highly solvatochromic and significantly enhanced as compared with that of the partial structures.

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          Author and article information

          Journal
          Chem Asian J
          Chemistry, an Asian journal
          Wiley-Blackwell
          1861-471X
          1861-471X
          Apr 2014
          : 9
          : 4
          Affiliations
          [1 ] Chemical Resources Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan), Fax: (+81) 45-924-5230.
          Article
          10.1002/asia.201301648
          24482401
          b82e0a71-eb3f-41cb-bfdd-fef25336d1e4
          History

          macrocycles,fluorophore,solvatochromism,anthracene,fluorescence

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