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      Improved electrical performance of a sol–gel IGZO transistor with high-k Al 2O 3 gate dielectric achieved by post annealing

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          Abstract

          We have explored the effect of post-annealing on the electrical properties of an indium gallium zinc oxide (IGZO) transistor with an Al 2O 3 bottom gate dielectric, formed by a sol–gel process. The post-annealed IGZO device demonstrated improved electrical performance in terms of threshold variation, on/off ratio, subthreshold swing, and mobility compared to the non-annealed reference device. Capacitance–voltage measurement confirmed that annealing can lead to enhanced capacitance properties due to reduced charge trapping. Depth profile analysis using X-ray photoelectron spectroscopy proved that percentage of both the oxygen vacancy (V O) and the hydroxyl groups (M–OH) within the IGZO/Al 2O 3 layers, which serve as a charge trapping source, can be substantially reduced by annealing the fabricated transistor device. Furthermore, the undesired degradation of the contact interface between source/drain electrode and the channel, which mainly concerns V O, can be largely prevented by post-annealing. Thus, the facile annealing process also improves the electrical bias stress stability. This simple post annealing approach provides a strategy for realising better performance and reliability of the solid sol–gel oxide transistor.

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          The online version of this article (10.1186/s40580-019-0194-1) contains supplementary material, which is available to authorized users.

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          Room-temperature fabrication of transparent flexible thin-film transistors using amorphous oxide semiconductors.

          Transparent electronic devices formed on flexible substrates are expected to meet emerging technological demands where silicon-based electronics cannot provide a solution. Examples of active flexible applications include paper displays and wearable computers. So far, mainly flexible devices based on hydrogenated amorphous silicon (a-Si:H) and organic semiconductors have been investigated. However, the performance of these devices has been insufficient for use as transistors in practical computers and current-driven organic light-emitting diode displays. Fabricating high-performance devices is challenging, owing to a trade-off between processing temperature and device performance. Here, we propose to solve this problem by using a novel semiconducting material--namely, a transparent amorphous oxide semiconductor from the In-Ga-Zn-O system (a-IGZO)--for the active channel in transparent thin-film transistors (TTFTs). The a-IGZO is deposited on polyethylene terephthalate at room temperature and exhibits Hall effect mobilities exceeding 10 cm2 V(-1) s(-1), which is an order of magnitude larger than for hydrogenated amorphous silicon. TTFTs fabricated on polyethylene terephthalate sheets exhibit saturation mobilities of 6-9 cm2 V(-1) s(-1), and device characteristics are stable during repetitive bending of the TTFT sheet.
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            Review of recent developments in amorphous oxide semiconductor thin-film transistor devices

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              High-pressure Gas Activation for Amorphous Indium-Gallium-Zinc-Oxide Thin-Film Transistors at 100 °C

              We investigated the use of high-pressure gases as an activation energy source for amorphous indium-gallium-zinc-oxide (a-IGZO) thin film transistors (TFTs). High-pressure annealing (HPA) in nitrogen (N2) and oxygen (O2) gases was applied to activate a-IGZO TFTs at 100 °C at pressures in the range from 0.5 to 4 MPa. Activation of the a-IGZO TFTs during HPA is attributed to the effect of the high-pressure environment, so that the activation energy is supplied from the kinetic energy of the gas molecules. We reduced the activation temperature from 300 °C to 100 °C via the use of HPA. The electrical characteristics of a-IGZO TFTs annealed in O2 at 2 MPa were superior to those annealed in N2 at 4 MPa, despite the lower pressure. For O2 HPA under 2 MPa at 100 °C, the field effect mobility and the threshold voltage shift under positive bias stress were improved by 9.00 to 10.58 cm2/V.s and 3.89 to 2.64 V, respectively. This is attributed to not only the effects of the pressurizing effect but also the metal-oxide construction effect which assists to facilitate the formation of channel layer and reduces oxygen vacancies, served as electron trap sites.
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                Author and article information

                Contributors
                bjcho@chungbuk.ac.kr
                Journal
                Nano Converg
                Nano Converg
                Nano Convergence
                Springer Singapore (Singapore )
                2196-5404
                22 July 2019
                22 July 2019
                December 2019
                : 6
                : 24
                Affiliations
                [1 ]ISNI 0000 0000 9611 0917, GRID grid.254229.a, Department of Advanced Material Engineering, , Chungbuk National University, ; Chungbuk, 28644 Republic of Korea
                [2 ]ISNI 0000 0000 9980 6151, GRID grid.258690.0, Department of Electronic Material Engineering, , Korea Maritime and Ocean University, ; Busan, 49112 Republic of Korea
                Author information
                http://orcid.org/0000-0002-3885-8139
                Article
                194
                10.1186/s40580-019-0194-1
                6643007
                31328241
                b5fbb954-77b9-4bbf-b6c6-d8ad7bfbede2
                © The Author(s) 2019

                Open AccessThis article is distributed under the terms of the Creative Commons Attribution 4.0 International License ( http://creativecommons.org/licenses/by/4.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made.

                History
                : 15 April 2019
                : 1 July 2019
                Funding
                Funded by: FundRef http://dx.doi.org/10.13039/501100003661, Korea Institute for Advancement of Technology;
                Award ID: P0006704
                Funded by: Ministry of Science and ICT
                Award ID: 2017R1C1B1005076
                Award Recipient :
                Categories
                Research
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                © The Author(s) 2019

                indium gallium zinc oxide igzo,post annealing,capacitance–voltage measurement,x-ray photoelectron spectroscopy depth profiling,electrical bias stress stability

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