ScienceOpen: research and publishing network

For Researchers

Search
Advanced search

0

views

    

0

recommends

0

shares

Record: found
Abstract: found
Article: not found

Cyanide-Free Cyanation of Aryl Iodides with Nitromethane by Using an Amphiphilic Polymer-Supported Palladium Catalyst

Author(s): Toshimasa Suzuka ¹ , Ryoko Niimi ¹ ^, ² , Yasuhiro Uozumi ¹ ^, ²

Publication date Created: December 16 2021

Publication date (Electronic): November 16 2021

Journal: Synlett

Publisher: Georg Thieme Verlag KG

Read this article at

ScienceOpenPublisher

There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

Abstract

A cyanide-free aromatic cyanation was developed that uses nitromethane as a cyanide source in water with an amphiphilic polystyrene–poly(ethylene glycol) resin-supported palladium catalyst and an alkyl halide (1-iodobutane). The cyanation proceeds through the palladium-catalyzed cross-coupling of an aryl halide with nitromethane, followed by transformation of the resultant (nitromethyl)arene intermediate into a nitrile by 1-iodobutane.

Related collections

Most cited references 8

Record: found
Abstract: not found
Article: not found

Synthesis of Aromatic Nitriles Using Nonmetallic Cyano-Group Sources

Jinho Kim, Hyun Jin Kim, Sukbok Chang (2012)

0 comments Cited 39 times – based on 0 reviews      Review now

Record: found
Abstract: not found
Article: not found

A convenient and efficient procedure for the palladium-catalyzed cyanation of aryl halides using trimethylsilylcyanide

Sateesh Mutyala, Alexander Zapf, Anke Spannenberg … (2003)

0 comments Cited 34 times – based on 0 reviews      Review now

Record: found
Abstract: not found
Article: not found

Convenient Transformation of Optically Active Nitroalkanes into Chiral Aldoximes and Nitriles

Constantin Czekelius, Erick M. Carreira (2005)

0 comments Cited 16 times – based on 0 reviews      Review now

Author and article information

Contributors

Yasuhiro Uozumi: (View ORCID Profile)

Journal

Title: Synlett

Abbreviated Title: Synlett

Publisher: Georg Thieme Verlag KG

ISSN (Print): 0936-5214

ISSN (Electronic): 1437-2096

Publication date Created: December 16 2021

Publication date Created: January 2022

Publication date Other: October 20 2021

Publication date (Electronic): November 16 2021

Publication date (Print): January 2022

Volume: 33

Issue: 01

Pages: 40-44

Affiliations

[1 ]Institute for Molecular Science (IMS)

[2 ]SOKENDAI, The Graduate University for Advanced Studies

Article

DOI: 10.1055/a-1675-0018

SO-VID: b52984cc-73ea-47a2-a8ef-bef33d878cd3

Copyright © © 2022

History

Data availability:

Comments

Comment on this article