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      Advances in helicene derivatives with circularly polarized luminescence

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          Abstract

          This review summarizes the recent research progress of helicenes and their derivatives with circularly polarized luminescence properties.

          Abstract

          Chiral materials have been widely present in people's lives, and their in-depth application research is underway. Generally, the circularly polarized light obtained from nonpolarized light through filters would result in brightness loss. Scientists have found that chirality can be introduced into organic compounds to obtain circularly polarized luminescence (CPL). Chiral compounds with CPL properties have attracted great attention and interest in recent years for their wide potential applications in 3D information displays, quantum communication, spintronics information storage, CPL lasers, nonlinear optics, biological probes and other fields. It is worth noting that helicene derivatives with twisted extended π-conjugated molecular structures could exhibit special helical chirality and excellent CPL properties. A chiral helix has also proven to be a valuable structural design for exploring small organic molecules with CPL. This review summarizes the recent development of CPL based on helicene derivatives.

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          Helicenes: synthesis and applications.

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            Supramolecular Helical Systems: Helical Assemblies of Small Molecules, Foldamers, and Polymers with Chiral Amplification and Their Functions.

            In this review, we describe the recent advances in supramolecular helical assemblies formed from chiral and achiral small molecules, oligomers (foldamers), and helical and nonhelical polymers from the viewpoints of their formations with unique chiral phenomena, such as amplification of chirality during the dynamic helically assembled processes, properties, and specific functionalities, some of which have not been observed in or achieved by biological systems. In addition, a brief historical overview of the helical assemblies of small molecules and remarkable progress in the synthesis of single-stranded and multistranded helical foldamers and polymers, their properties, structures, and functions, mainly since 2009, will also be described.
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              Circularly Polarized Luminescence in Nanoassemblies: Generation, Amplification, and Application

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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                CHCOFS
                Chemical Communications
                Chem. Commun.
                Royal Society of Chemistry (RSC)
                1359-7345
                1364-548X
                November 14 2019
                2019
                : 55
                : 92
                : 13793-13803
                Affiliations
                [1 ]University of Chinese Academy of Sciences
                [2 ]Beijing 100049
                [3 ]China
                [4 ]Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Molecular Recognition and Function
                [5 ]Institute of Chemistry
                [6 ]Chinese Academy of Sciences
                [7 ]Beijing 100190
                Article
                10.1039/C9CC06861A
                b3f764d9-c110-4497-a470-cacf02ea4eb3
                © 2019

                http://rsc.li/journals-terms-of-use

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