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      Desaromatisierungsstrategien in der Synthese strukturell komplexer Naturstoffe

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      Angewandte Chemie
      Wiley-Blackwell

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          Nucleus-independent chemical shifts (NICS) as an aromaticity criterion.

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            Structural aspects of aromaticity.

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              The application of cathodic reductions and anodic oxidations in the synthesis of complex molecules.

              This tutorial review surveys the recent advances in electrochemical transformations as they pertain to the synthesis of complex organic molecules. Electrochemistry has emerged as a powerful tool to synthetic chemists, yet many have never considered electrochemical methodology as a means for synthesis. Here, an introduction to electrochemistry and voltammetry will be provided with descriptions of the four types of electrochemical cells. In addition, recent examples of both anodic oxidations and cathodic reductions will be discussed, along with the experimental setups for carrying out each reaction.
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                Author and article information

                Journal
                Angewandte Chemie
                Angew. Chem.
                Wiley-Blackwell
                00448249
                April 26 2011
                April 26 2011
                : 123
                : 18
                : 4154-4179
                Article
                10.1002/ange.201006017
                b1800d57-a450-4ece-a06c-df23212621d3
                © 2011

                http://doi.wiley.com/10.1002/tdm_license_1.1

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