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      Design and Application of Highly Efficient Flame Retardants for Polycarbonate Combining the Advantages of Cyclotriphosphazene and Silicone Oil

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          Abstract

          A novel flame retardant (HSPCTP) was successfully designed and incorporated into a polycarbonate (PC) matrix. Combining the advantages of cyclotriphosphazene and silicone oil, PC/HSPCTP composites passed UL-94 V-0 rating testing with only 3 wt% HSPCTP, and their LOI value increased from 25.0% to 28.4%. The findings showed that HSPCTP exhibits both gas-phase and solid-phase flame-retardant effects. Furthermore, the incorporation of HSPCTP into PC could suppress the release of smoke. Finally, the flame-retardant mechanism is discussed in depth.

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          Most cited references42

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          Recent developments in the chemistry of halogen-free flame retardant polymers

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            Flame retardancy of silicone-based materials

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              Thermal degradation behavior of the compound containing phosphaphenanthrene and phosphazene groups and its flame retardant mechanism on epoxy resin

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                Author and article information

                Journal
                Polymers (Basel)
                Polymers (Basel)
                polymers
                Polymers
                MDPI
                2073-4360
                05 July 2019
                July 2019
                : 11
                : 7
                : 1155
                Affiliations
                Jiangsu Key Laboratory of Environmentally Friendly Polymeric Materials, School of Materials Science and Engineering, Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering, Changzhou University, Changzhou 213164, Jiangsu, China
                Author notes
                [* ]Correspondence: wangyanbin@ 123456cczu.edu.cn (Y.W.); biaobing@ 123456cczu.edu.cn (B.W.); Tel.: +86-519-8633-0095 (Y.W.); +86-519-8633-0075 (B.W.)
                Author information
                https://orcid.org/0000-0002-7085-1025
                Article
                polymers-11-01155
                10.3390/polym11071155
                6680785
                31284539
                b1694aa0-4fde-4377-8231-0a611aa4ad72
                © 2019 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 17 June 2019
                : 04 July 2019
                Categories
                Article

                triphosphazene,flame retardant,silicone oil,polycarbonate

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