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      Recent advances in noble metal based composite nanocatalysts: colloidal synthesis, properties, and catalytic applications

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          Abstract

          This Review article provides a report on progress in the synthesis, properties and catalytic applications of noble metal based composite nanomaterials.

          Abstract

          This Review article provides a report on progress in the synthesis, properties and catalytic applications of noble metal based composite nanomaterials. We begin with a brief discussion on the categories of various composite materials. We then present some important colloidal synthetic approaches to the composite nanostructures; here, major attention has been paid to bimetallic nanoparticles. We also introduce some important physiochemical properties that are beneficial from composite nanomaterials. Finally, we highlight the catalytic applications of such composite nanoparticles and conclude with remarks on prospective future directions.

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          Most cited references307

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          Monodisperse FePt nanoparticles and ferromagnetic FePt nanocrystal superlattices

          Sun, Murray, Weller (2000)
          Synthesis of monodisperse iron-platinum (FePt) nanoparticles by reduction of platinum acetylacetonate and decomposition of iron pentacarbonyl in the presence of oleic acid and oleyl amine stabilizers is reported. The FePt particle composition is readily controlled, and the size is tunable from 3- to 10-nanometer diameter with a standard deviation of less than 5%. These nanoparticles self-assemble into three-dimensional superlattices. Thermal annealing converts the internal particle structure from a chemically disordered face-centered cubic phase to the chemically ordered face-centered tetragonal phase and transforms the nanoparticle superlattices into ferromagnetic nanocrystal assemblies. These assemblies are chemically and mechanically robust and can support high-density magnetization reversal transitions.
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            Localized surface plasmon resonance sensors.

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              Pd-Pt bimetallic nanodendrites with high activity for oxygen reduction.

              Controlling the morphology of Pt nanostructures can provide a great opportunity to improve their catalytic properties and increase their activity on a mass basis. We synthesized Pd-Pt bimetallic nanodendrites consisting of a dense array of Pt branches on a Pd core by reducing K2PtCl4 with L-ascorbic acid in the presence of uniform Pd nanocrystal seeds in an aqueous solution. The Pt branches supported on faceted Pd nanocrystals exhibited relatively large surface areas and particularly active facets toward the oxygen reduction reaction (ORR), the rate-determining step in a proton-exchange membrane fuel cell. The Pd-Pt nanodendrites were two and a half times more active on the basis of equivalent Pt mass for the ORR than the state-of-the-art Pt/C catalyst and five times more active than the first-generation supportless Pt-black catalyst.
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                Author and article information

                Journal
                NANOHL
                Nanoscale
                Nanoscale
                Royal Society of Chemistry (RSC)
                2040-3364
                2040-3372
                2015
                2015
                : 7
                : 24
                : 10559-10583
                Affiliations
                [1 ]Jiangsu Key Laboratory for Carbon-Based Functional Materials & Devices
                [2 ]Institute of Functional Nano and Soft Materials (FUNSOM) and Collaborative Innovation Center of Suzhou Nano Science and Technology
                [3 ]Soochow University
                [4 ]Suzhou 215123, P. R. China
                [5 ]Joint Laboratory for Extreme Conditions Matter Properties
                [6 ]Southwest University of Science and Technology
                [7 ]Mianyang, China
                Article
                10.1039/C5NR02216A
                26036784
                ae83f3e4-6443-4c91-8808-6d3e8f2b2719
                © 2015
                History

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