Cationic nickel porphyrinoids with unexpected reactivity † †Electronic supplementary information (ESI) available: Preparation and analytical data of  7  and  8 ; details of DFT calculations and catalytic investigations. CCDC  1057061 . For ESI and crystallographic data in CIF or other electronic format see DOI:  10.1039/c5sc03663a

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Abstract

Nickel(II) complexes of ring-contracted 9-methylisocorroles were prepared by templated macrocyclisation and act as the first porphyrinoid catalysts for C–C cross-coupling.

Abstract

Cationic nickel( ii) complexes of two ring-contracted porphyrinoid ligands distantly related to the corrins were prepared by metal templated macrocyclisation. The compounds show reversible electron transfer processes and were found to be the first porphyrinoid-based catalysts for C–C cross-coupling.

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Author and article information

Journal

Journal ID (nlm-ta): Chem Sci

Journal ID (iso-abbrev): Chem Sci

Title: Chemical Science

Publisher: Royal Society of Chemistry

ISSN (Print): 2041-6520

ISSN (Electronic): 2041-6539

Publication date (Print): 1 January 2016

Publication date (Electronic): 16 October 2015

Volume: 7

Issue: 1

Pages: 583-588

Affiliations

[a ] Institute for Inorganic and Analytical Chemistry , Technical University Braunschweig , Hagenring 30 , 38106 Braunschweig , Germany . Email: m.broering@ 123456tu-bs.de

Article

Publisher ID: c5sc03663a

DOI: 10.1039/c5sc03663a

PMC ID: 5952870

SO-VID: ae32b40b-c03b-4af1-a0d8-f1fa82fb5bac

License:

This article is freely available. This article is licensed under a Creative Commons Attribution Non Commercial 3.0 Unported Licence (CC BY-NC 3.0)

History

Date received : 26 September 2015

Date accepted : 13 October 2015

Notes

†Electronic supplementary information (ESI) available: Preparation and analytical data of 7 and 8; details of DFT calculations and catalytic investigations. CCDC 1057061. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc03663a

Data availability:

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