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      Study on Tribological Properties and Mechanisms of Different Morphology WS 2 as Lubricant Additives

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          Abstract

          In the present work, the relationship curve of the coefficient of friction (COF) with varying loads of different morphology WS 2 lubricating additives in the friction process at various sliding speeds was studied. On this basis, wear marks and elements on the wear surfaces after friction were analyzed, and then the anti-wear and mechanism effects of WS 2 of different forms in the lubrication process were discussed. Meanwhile, the Stribeck curve was used to study the lubrication state of the lubricating oil in the friction process. It was revealed that the COF of lubricating oil containing lamellar WS 2 decreased by 29.35% at optimum condition and the minimum COF was concentrated at around 100 N. The COF of lubricating oil containing spherical WS 2 decreased by 30.24% and the minimum coefficient was concentrated at 120 N. The extreme pressure property of spherical WS 2 was better than that of lamellar WS 2, and the wear resistance of spherical WS 2 was more stable when the load was over 80 N. The different morphology of WS 2 additives can play anti-wear and anti-friction roles within a wide range of sliding speeds.

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          Contact and Rubbing of Flat Surfaces

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            Roles of nanoparticles in oil lubrication

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              Organic-Modified Silver Nanoparticles as Lubricant Additives.

              Advanced lubrication is essential in human life for improving mobility, durability, and efficiency. Here we report the synthesis, characterization, and evaluation of two groups of oil-suspendable silver nanoparticles (NPs) as candidate lubricant additives. Two types of thiolated ligands, 4-(tert-butyl)benzylthiol (TBBT) and dodecanethiol (C12), were used to modify Ag NPs in two size ranges, 1-3 and 3-6 nm. The organic surface layer successfully suspended the Ag NPs in a poly-alpha-olefin (PAO) base oil with concentrations up to 0.19-0.50 wt %, depending on the particle type. Use of the Ag NPs in the base oil reduced friction by up to 35% and wear by up to 85% in boundary lubrication. The two TBBT-modified NPs produced a lower friction coefficient than the C12-modified one, while the two larger NPs (3-6 nm) had better wear protection than the smaller one (1-3 nm). Results suggested that the molecular structure of the organic ligand might have a dominant effect on the friction behavior, while the NP size could be more influential in the wear protection. No mini-ball-bearing or surface smoothening effects were observed in the Stribeck scans. Instead, the wear protection in boundary lubrication was attributed to the formation of a silver-rich 50-100 nm thick tribofilm on the worn surface, as revealed by morphology examination and composition analysis from both the top surface and cross section.
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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                26 March 2020
                April 2020
                : 13
                : 7
                : 1522
                Affiliations
                [1 ]School of Mechanical & Electrical Engineering, Jiangsu Normal University, Xuzhou 221116, China; huning_ning@ 123456163.com (N.H.); 18852172825@ 123456163.com (X.Z.); m18362982507@ 123456163.com (X.W.)
                [2 ]School of Mechanical & Electrical Engineering, China University of Mining & Technology, Xuzhou 221116, China
                Author notes
                [* ]Correspondence: wuna1123@ 123456cumt.edu.cn (N.W.); wbplsz@ 123456163.com (S.W.); Tel.: +86-1836-124-5068 (N.W.); +86-1358-547-8569 (S.W.)
                Author information
                https://orcid.org/0000-0002-0711-898X
                https://orcid.org/0000-0003-4133-0025
                Article
                materials-13-01522
                10.3390/ma13071522
                7178242
                32224989
                a677024a-fd2e-45a5-954d-72d1b7f0ee36
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 25 February 2020
                : 23 March 2020
                Categories
                Article

                ws2,anti-wear,anti-friction,lubricant additives,tribological properties

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