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      Anaerobic Digestion for Producing Renewable Energy—The Evolution of This Technology in a New Uncertain Scenario

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          Abstract

          Anaerobic digestion is a well-known technology with wide application in the treatment of high-strength organic wastes. The economic feasibility of this type of installation is usually attained thanks to the availability of fiscal incentives. In this review, an analysis of the different factors associated with this biological treatment and a description of alternatives available in literature for increasing performance of the process were provided. The possible integration of this process into a biorefinery as a way for producing energy and chemical products from the conversion of wastes and biomass also analyzed. The future outlook of anaerobic digestion will be closely linked to circular economy principles. Therefore, this technology should be properly integrated into any production system where energy can be recovered from organics. Digestion can play a major role in any transformation process where by-products need further stabilization or it can be the central core of any waste treatment process, modifying the current scheme by a concatenation of several activities with the aim of increasing the efficiency of the conversion. Thus, current plants dedicated to the treatment of wastewaters, animal manures, or food wastes can become specialized centers for producing bio-energy and green chemicals. However, high installation costs, feedstock dispersion and market distortions were recognized as the main parameters negatively affecting these alternatives.

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          Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance

          Although measurements of crystallinity index (CI) have a long history, it has been found that CI varies significantly depending on the choice of measurement method. In this study, four different techniques incorporating X-ray diffraction and solid-state 13C nuclear magnetic resonance (NMR) were compared using eight different cellulose preparations. We found that the simplest method, which is also the most widely used, and which involves measurement of just two heights in the X-ray diffractogram, produced significantly higher crystallinity values than did the other methods. Data in the literature for the cellulose preparation used (Avicel PH-101) support this observation. We believe that the alternative X-ray diffraction (XRD) and NMR methods presented here, which consider the contributions from amorphous and crystalline cellulose to the entire XRD and NMR spectra, provide a more accurate measure of the crystallinity of cellulose. Although celluloses having a high amorphous content are usually more easily digested by enzymes, it is unclear, based on studies published in the literature, whether CI actually provides a clear indication of the digestibility of a cellulose sample. Cellulose accessibility should be affected by crystallinity, but is also likely to be affected by several other parameters, such as lignin/hemicellulose contents and distribution, porosity, and particle size. Given the methodological dependency of cellulose CI values and the complex nature of cellulase interactions with amorphous and crystalline celluloses, we caution against trying to correlate relatively small changes in CI with changes in cellulose digestibility. In addition, the prediction of cellulase performance based on low levels of cellulose conversion may not include sufficient digestion of the crystalline component to be meaningful.
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            Trends in bioconversion of lignocellulose: Biofuels, platform chemicals & biorefinery concept

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              Electrochemical oxidation of organic pollutants for the wastewater treatment: direct and indirect processes.

              In recent years, there has been increasing interest in finding innovative solutions for the efficient removal of contaminants from water, soil and air. The present tutorial review summarizes the results of an extensive selection of papers dealing with electrochemical oxidation, which is proposed as an alternative for treating polluted wastes. Both the direct and indirect approaches are considered, and the role of electrode materials is discussed together with that of other experimental parameters. Apart from discussing the possibility of removing selected contaminants from water using different anodes, efficiency rates for pollutant removal have been collected, the dependence of these rates on operational conditions advantages and disadvantages determining the further full-scale commercial application.
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                Author and article information

                Journal
                Entropy (Basel)
                Entropy (Basel)
                entropy
                Entropy
                MDPI
                1099-4300
                25 January 2021
                February 2021
                : 23
                : 2
                : 145
                Affiliations
                [1 ]Chemical and Environmental Bioprocess Engineering Group, Natural Resources Institute (IRENA), Universidad de León, Av. de Portugal 41, 24009 León, Spain; cares@ 123456unileon.es (C.A.S.); ejmartr@ 123456unileon.es (E.J.M.)
                [2 ]Departamento de Química y Física Aplicadas, Campus de Vegazana, University of León, 24071 León, Spain; alby.aguilar@ 123456gmail.com
                [3 ]Escuela Superior Politécnica del Litoral (ESPOL), Facultad de Ingeniería en Ciencias de la Tierra, Guayaquil EC090112, Ecuador; gepena@ 123456espol.edu.ec
                Author notes
                [* ]Correspondence: xagomb@ 123456unileon.es
                Author information
                https://orcid.org/0000-0001-7625-7636
                https://orcid.org/0000-0002-4426-4353
                https://orcid.org/0000-0001-9595-8825
                Article
                entropy-23-00145
                10.3390/e23020145
                7912667
                33503933
                a0b9c96e-2e58-44b6-beaf-865bbefb4dfd
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 28 December 2020
                : 20 January 2021
                Categories
                Review

                biogas valorization,lignocellulosic pre-treatment,techno-economic performance,process integration,energy production

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