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      Mechanically stable, hierarchically porous Cu3(btc)2 (HKUST-1) monoliths via direct conversion of copper(ii) hydroxide-based monoliths

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          Abstract

          Robust, hierarchically porous Cu 3(btc) 2 (HKUST-1, btc 3− = benzene-1,3,5-tricalboxylate) monoliths have been synthesized by direct conversion of sol–gel-derived Cu(OH) 2-based monoliths.

          Abstract

          The synthesis of highly crystalline macro-meso-microporous monolithic Cu 3(btc) 2 (HKUST-1; btc 3− = benzene-1,3,5-tricarboxylate) is demonstrated by direct conversion of Cu(OH) 2-based monoliths while preserving the characteristic macroporous structure. The high mechanical strength of the monoliths is promising for possible applications to continuous flow reactors.

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          Functional Porous Coordination Polymers

          Susumu Kitagawa, Ryo Kitaura, Shin-ichiro Noro (2004)
          The chemistry of the coordination polymers has in recent years advanced extensively, affording various architectures, which are constructed from a variety of molecular building blocks with different interactions between them. The next challenge is the chemical and physical functionalization of these architectures, through the porous properties of the frameworks. This review concentrates on three aspects of coordination polymers: 1). the use of crystal engineering to construct porous frameworks from connectors and linkers ("nanospace engineering"), 2). characterizing and cataloging the porous properties by functions for storage, exchange, separation, etc., and 3). the next generation of porous functions based on dynamic crystal transformations caused by guest molecules or physical stimuli. Our aim is to present the state of the art chemistry and physics of and in the micropores of porous coordination polymers.
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            The pervasive chemistry of metal-organic frameworks.

            Jeffrey R Long, Omar Yaghi (2009)
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              MOF thin films: existing and future applications.

              O Shekhah, J. Liu, R A Fischer … (2011)
              The applications and potentials of thin film coatings of metal-organic frameworks (MOFs) supported on various substrates are discussed in this critical review. Because the demand for fabricating such porous coatings is rather obvious, in the past years several synthesis schemes have been developed for the preparation of thin porous MOF films. Interestingly, although this is an emerging field seeing a rapid development a number of different applications on MOF films were either already demonstrated or have been proposed. This review focuses on the fabrication of continuous, thin porous films, either supported on solid substrates or as free-standing membranes. The availability of such two-dimensional types of porous coatings opened the door for a number of new perspectives for functionalizing surfaces. Also for the porous materials themselves, the availability of a solid support to which the MOF-films are rigidly (in a mechanical sense) anchored provides access to applications not available for the typical MOF powders with particle sizes of a few μm. We will also address some of the potential and applications of thin films in different fields like luminescence, QCM-based sensors, optoelectronics, gas separation and catalysis. A separate chapter has been devoted to the delamination of MOF thin films and discusses the potential to use them as free-standing membranes or as nano-containers. The review also demonstrates the possibility of using MOF thin films as model systems for detailed studies on MOF-related phenomena, e.g. adsorption and diffusion of small molecules into MOFs as well as the formation mechanism of MOFs (101 references).
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                Author and article information

                Journal
                Journal ID (publisher-id): CHCOFS
                Title: Chemical Communications
                Abbreviated Title: Chem. Commun.
                Publisher: Royal Society of Chemistry (RSC)
                ISSN (Print): 1359-7345
                ISSN (Electronic): 1364-548X
                Publication date Created: 2015
                Publication date (Electronic): 2015
                Volume: 51
                Issue: 17
                Pages: 3511-3514
                Affiliations
                [1 ]Department of Chemistry
                [2 ]Graduate School of Science
                [3 ]Kyoto University
                [4 ]Sakyo-ku
                [5 ]Japan
                [6 ]Institute for Integrated Cell-Material Sciences (WPI-iCeMS)
                Article
                DOI: 10.1039/C4CC09694K
                SO-VID: a02d8658-ab36-4761-812f-799cad46946c
                Copyright © © 2015
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