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      Materials for hydrogen storage

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      Journal: Materials Today
      Publisher: Elsevier BV

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          Hydrogen storage in microporous metal-organic frameworks.

          Nathaniel Rosi, Juergen Eckert, Mohamed Eddaoudi … (2003)
          Metal-organic framework-5 (MOF-5) of composition Zn4O(BDC)3 (BDC = 1,4-benzenedicarboxylate) with a cubic three-dimensional extended porous structure adsorbed hydrogen up to 4.5 weight percent (17.2 hydrogen molecules per formula unit) at 78 kelvin and 1.0 weight percent at room temperature and pressure of 20 bar. Inelastic neutron scattering spectroscopy of the rotational transitions of the adsorbed hydrogen molecules indicates the presence of two well-defined binding sites (termed I and II), which we associate with hydrogen binding to zinc and the BDC linker, respectively. Preliminary studies on topologically similar isoreticular metal-organic framework-6 and -8 (IRMOF-6 and -8) having cyclobutylbenzene and naphthalene linkers, respectively, gave approximately double and quadruple (2.0 weight percent) the uptake found for MOF-5 at room temperature and 10 bar.
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            Processes of adsorption and diffusion on solid surfaces

            J E Lennard-Jones (1932)
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              LiBH4 a new hydrogen storage material

              P. Sudan, P. Wenger, A Züttel … (2003)
              Article 0 comments Cited 131 times – based on 0 reviews     Review now
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                Author and article information

                Journal
                Title: Materials Today
                Abbreviated Title: Materials Today
                Publisher: Elsevier BV
                ISSN (Print): 13697021
                Publication date Created: September 2003
                Publication date (Print): September 2003
                Volume: 6
                Issue: 9
                Pages: 24-33
                Article
                DOI: 10.1016/S1369-7021(03)00922-2
                SO-VID: 9fc3c7ad-e301-4753-86f6-8d26f3a4f68e
                Copyright © © 2003
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                http://www.elsevier.com/tdm/userlicense/1.0/

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