Helical Spin Dynamics in Commensurate Magnets: a Study on Brochantite, Cu\(_4\)SO\(_4\)(OH)\(_6\)

Abstract

We report the direct observation of a commensurate-ordered antiferromagnetic (AFM) state but incommensurate helical spin dynamics in the natural mineral brochantite Cu\(_4\)SO\(_4\)(OH)\(_6\) through neutron diffraction and neutron spectroscopy measurements. Inelastic neutron scattering measurements reveal magnon-like excitations with considerable dispersion along the c-axis and almost flat branches in other principal directions, indicating the strong one-dimensional character of the magnetic correlations. We experimentally observe the effect of the uniform Dzyaloshinskii-Moriya (DM) interaction, which elevates the degeneracy of the spin-wave modes shifting them in opposite directions in reciprocal space. The system has a commensurate AFM ground state, stabilized by the anisotropic symmetric Heisenberg exchange interactions, and quasi-one-dimensional chiral spin dynamics due to the antisymmetric DM interaction. Employing linear spin-wave theory, we were able to construct an effective Heisenberg Hamiltonian. We quantify both the symmetric exchange parameters and the DM vector components in Cu\(_4\)SO\(_4\)(OH)\(_6\) and determine the mechanism of the magnetic frustration. Our work provides detailed insights into the complex dynamics of the spin chain in the presence of uniform DM interaction.