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      Evaluation of Integrated Anaerobic Digestion and Hydrothermal Carbonization for Bioenergy Production

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          Abstract

          Lignocellulosic biomass is one of the most abundant yet underutilized renewable energy resources. Both anaerobic digestion (AD) and hydrothermal carbonization (HTC) are promising technologies for bioenergy production from biomass in terms of biogas and HTC biochar, respectively. In this study, the combination of AD and HTC is proposed to increase overall bioenergy production. Wheat straw was anaerobically digested in a novel upflow anaerobic solid state reactor (UASS) in both mesophilic (37 °C) and thermophilic (55 °C) conditions. Wet digested from thermophilic AD was hydrothermally carbonized at 230 °C for 6 hr for HTC biochar production. At thermophilic temperature, the UASS system yields an average of 165 L CH4/kg VS (VS: volatile solids) and 121 L CH4/kg VS at mesophilic AD over the continuous operation of 200 days. Meanwhile, 43.4 g of HTC biochar with 29.6 MJ/kg dry_biochar was obtained from HTC of 1 kg digestate (dry basis) from mesophilic AD. The combination of AD and HTC, in this particular set of experiment yield 13.2 MJ of energy per 1 kg of dry wheat straw, which is at least 20% higher than HTC alone and 60.2% higher than AD only.

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          Thermochemical biofuel production in hydrothermal media: A review of sub- and supercritical water technologies

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            Hydrothermal carbonization of municipal waste streams.

            Hydrothermal carbonization (HTC) is a novel thermal conversion process that can be used to convert municipal waste streams into sterilized, value-added hydrochar. HTC has been mostly applied and studied on a limited number of feedstocks, ranging from pure substances to slightly more complex biomass such as wood, with an emphasis on nanostructure generation. There has been little work exploring the carbonization of complex waste streams or of utilizing HTC as a sustainable waste management technique. The objectives of this study were to evaluate the environmental implications associated with the carbonization of representative municipal waste streams (including gas and liquid products), to evaluate the physical, chemical, and thermal properties of the produced hydrochar, and to determine carbonization energetics associated with each waste stream. Results from batch carbonization experiments indicate 49-75% of the initially present carbon is retained within the char, while 20-37% and 2-11% of the carbon is transferred to the liquid- and gas-phases, respectively. The composition of the produced hydrochar suggests both dehydration and decarboxylation occur during carbonization, resulting in structures with high aromaticities. Process energetics suggest feedstock carbonization is exothermic.
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              Hydrothermal Carbonization (HTC) of Lignocellulosic Biomass

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                Author and article information

                Journal
                J Vis Exp
                J Vis Exp
                JoVE
                Journal of Visualized Experiments : JoVE
                MyJove Corporation
                1940-087X
                2014
                15 June 2014
                15 June 2014
                : 88
                : 51734
                Affiliations
                1APECS Group, Leibniz Institute for Agricultural Engineering
                Author notes

                Correspondence to: M. Toufiq Reza at TReza@ 123456atb-potsdam.de

                Article
                51734
                10.3791/51734
                4189747
                24962786
                95e035bb-bb10-40c2-8e62-8a5b58bc4de9
                Copyright © 2014, Journal of Visualized Experiments

                This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial License, which permits non-commercial use, distribution, and reproduction, provided the original work is properly cited.

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                Categories
                Environmental Sciences

                Uncategorized
                environmental sciences,issue 88,biomethane,hydrothermal carbonization (htc),calorific value,lignocellulosic biomass,uass,anaerobic digestion

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