[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver atoms.

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Abstract

We report the total structure determination of a covalently bonded nanocluster polymer [Au7Ag9(dppf)3(CF3CO2)7BF4]n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au7Ag8(dppf)3(CF3CO2)7 clusters, which are linked together by Ag-O bonds rather than Au-Au interactions or bidentate organic bridges as previously reported.

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Journal

Journal ID (iso-abbrev): Chem Commun (Camb)

Title: Chemical communications (Cambridge, England)

Publisher: Royal Society of Chemistry (RSC)

ISSN (Electronic): 1364-548X

ISSN (Print): 1359-7345

Publication date (Electronic): Oct 24 2019

Volume: 55

Issue: 86

Affiliations

[1 ] Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China.

[2 ] Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China and Department of Chemistry, Tsinghua University, China. linyum@xmu.edu.cn.

Article

DOI: 10.1039/c9cc05924e

PubMed ID: 31608354

SO-VID: 942a55a0-5e6b-44e7-922e-b113db1ba064

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