Synthesis and characterization of a tetrathiafulvalene-salphen actinide complex.

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Abstract

A new tetrathiafulvalene-salphen uranyl complex has been prepared. The system was designed to study the electronic coupling between actinides and a redox active ligand framework. Theoretical and experimental methods--including DFT calculations, single crystal X-ray analysis, cyclic voltammetry, NMR and IR spectroscopies--were used to characterize this new uranyl complex.

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Journal

Journal ID (iso-abbrev): Dalton Trans

Title: Dalton transactions (Cambridge, England : 2003)

Publisher: Royal Society of Chemistry (RSC)

ISSN (Electronic): 1477-9234

ISSN (Print): 1477-9226

Publication date (Electronic): May 21 2013

Volume: 42

Issue: 19

Affiliations

[1 ] Department of Chemistry and Biochemistry and Institute for Cellular and Molecular Biology, The University of Texas at Austin, 105 E. 24th Street - Stop A5300, Austin, Texas 78712-1224, USA.

Article

DOI: 10.1039/c3dt50698c

PubMed ID: 23572119

SO-VID: 92f061f9-3b4f-4bcb-8edb-794072011cb8

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