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      Waste milk humification product can be used as a slow release nano-fertilizer

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          Abstract

          The demand for milk has increased globally, accompanied by an increase in waste milk. Here, we provide an artificial humification technology to recycle waste milk into an agricultural nano-fertilizer. We use KOH-activated persulfate to convert waste milk into fulvic-like acid and humic-like acid. We mix the product with attapulgite to obtain a slow-release nano fulvic-like acid fertilizer. We apply this nano-fertilizer to chickweeds growing in pots, resulting in improved yield and root elongation. These results indicate that waste milk could be recycled for agricultural purposes, however, this nano-fertilizer needs to be tested further in field experiments.

          Abstract

          The growth in global milk demand has been accompanied by an increase in waste milk disposal. Here, the authors transform waste milk through humification and incorporate the product into attapulgite creating a nano-fertiliser that benefits for plants growing in pots.

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          Most cited references62

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          Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks

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            Global agriculture and nitrous oxide emissions

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              Production of sulfate radical and hydroxyl radical by reaction of ozone with peroxymonosulfate: a novel advanced oxidation process.

              In this work, simultaneous generation of hydroxyl radical (•OH) and sulfate radical (SO4•−) by the reaction of ozone (O3) with peroxymonosulfate (PMS; HSO5−) has been proposed and experimentally verified. We demonstrate that the reaction between the anion of PMS (i.e.,SO52−) and O3 is primarily responsible for driving O3 consumption with a measured second order rate constant of (2.12 ± 0.03) × 10(4) M(-1) s(-1). The formation of both •OH and SO4•− from the reaction between SO52− and O3 is confirmed by chemical probes (i.e., nitrobenzene for •OH and atrazine forb oth •OH and SO4•−). The yields of •OH and SO4•− are determined to be 0.43 ± 0.1 and 0.45 ± 0.1 per mol of O3 consumption, respectively. An adduct,−O3SOO− + O3 → −O3SO5−, is assumed as the first step, which further decomposes into SO5•− and O3•−. The subsequent reaction of SO5•− with O3is proposed to generate SO4•−, while O3•− converts to •OH. A definition of R(ct,•OH) and R(ct,SO4•−) (i.e., respective ratios of •OH and SO4•− exposures to O3 exposure) is adopted to quantify relative contributions of •OH and SO4•−. Increasing pH leads to increases in both values of R(ct,•OH) and R(ct,SO4•−) but does not significantly affect the ratio of R(ct,SO4•−) to R(ct,•OH) (i.e., R(ct,SO4•−)/R(ct,•OH)), which represents the relative formation of SO4•− to •OH. The presence of bicarbonate appreciably inhibits the degradation of probes and fairly decreases the relative contribution of •OH for their degradation, which may be attributed to the conversion of both •OH and SO4•− to the more selective carbonate radical (CO3•−).Humic acid promotes O3 consumption to generate •OH and thus leads to an increase in the R(ct,•OH) value in the O3/PMS process,w hile humic acid has negligible influence on the R(ct,SO4•−) value. This discrepancy is reasonably explained by the negligible effect of humic acid on SO4•− formation and a lower rate constant for the reaction of humic acid with SO4•− than with •OH. In addition, the efficacy of the O3/PMS process in real water is also confirmed.
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                Author and article information

                Contributors
                dqcai@dhu.edu.cn
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                2 January 2024
                2 January 2024
                2024
                : 15
                : 128
                Affiliations
                [1 ]College of Environmental Science and Engineering, Donghua University, ( https://ror.org/035psfh38) Shanghai, 201620 People’s Republic of China
                [2 ]Department of Civil Engineering, University of Manitoba, ( https://ror.org/02gfys938) Winnipeg, MB R3T 5V6 Canada
                [3 ]Guangxi Subtropical Crops Research Institute, ( https://ror.org/01k56kn83) Nanning, 530000 People’s Republic of China
                [4 ]GRID grid.458488.d, ISNI 0000 0004 0627 1442, Institute of Microbiology, Chinese Academy of Sciences, ; 100101 Beijing, People’s Republic of China
                Author information
                http://orcid.org/0000-0003-2213-5638
                http://orcid.org/0000-0001-5279-2415
                Article
                44422
                10.1038/s41467-023-44422-5
                10761720
                38167856
                91fdffbe-0530-444b-aabf-7835bf401af7
                © The Author(s) 2024

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 1 March 2023
                : 13 December 2023
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                Custom metadata
                © Springer Nature Limited 2024

                Uncategorized
                pollution remediation,agroecology,environmental impact
                Uncategorized
                pollution remediation, agroecology, environmental impact

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