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      Development of a Novel Multifunctional Cementitious-Based Geocomposite by the Contribution of CNT and GNP

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          Abstract

          In this study, a self-sensing cementitious stabilized sand (CSS) was developed by the incorporation of hybrid carbon nanotubes (CNTs) and graphene nanoplatelets (GNPs) based on the piezoresistivity principle. For this purpose, different concentrations of CNTs and GNPs (1:1) were dispersed into the CSS, and specimens were fabricated using the standard compaction method with optimum moisture. The mechanical and microstructural, durability, and piezoresistivity performances, of CSS were investigated by various tests after 28 days of hydration. The results showed that the incorporation of 0.1%, 0.17%, and 0.24% CNT/GNP into the stabilized sand with 10% cement caused an increase in UCS of about 65%, 31%, and 14%, respectively, compared to plain CSS. An excessive increase in the CNM concentration beyond 0.24% to 0.34% reduced the UCS by around 13%. The addition of 0.1% CNMs as the optimum concentration increased the maximum dry density of the CSS as well as leading to optimum moisture reduction. Reinforcing CSS with the optimum concentration of CNT/GNP improved the hydration rate and durability of the specimens against severe climatic cycles, including freeze–thaw and wetting–drying. The addition of 0.1%, 0.17%, 0.24%, and 0.34% CNMs into the CSS resulted in gauge factors of about 123, 139, 151, and 173, respectively. However, the Raman and X-ray analysis showed the negative impacts of harsh climatic cycles on the electrical properties of the CNT/GNP and sensitivity of nano intruded CSS.

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          High Weight Fraction Surfactant Solubilization of Single-Wall Carbon Nanotubes in Water

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            The role of surfactants in dispersion of carbon nanotubes.

            The discovery of carbon nanotubes offers exciting opportunities for the development of novel high property materials. Disaggregation and uniform dispersion are critical challenges that must be met to successfully produce such high property materials, since carbon nanotubes tend to self-associate into micro-scale aggregates. This results in products with inferior mechanical and electric performance. Recognizing this problem, extensive research has been reported in the literature on development of dispersion technologies based on both mechanical and chemical approaches. Here, we review recent progress and advances that have been made on dispersion of carbon nanotubes in aqueous and organic media by non-covalent adsorption of surfactants and polymers. Carbon nanotube structure, properties and mainly self-assembly are discussed in detail.
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              Probing the Nature of Defects in Graphene by Raman Spectroscopy

              Raman spectroscopy is able to probe disorder in graphene through defect-activated peaks. It is of great interest to link these features to the nature of disorder. Here we present a detailed analysis of the Raman spectra of graphene containing different type of defects. We found that the intensity ratio of the D and D' peak is maximum (∼13) for sp(3)-defects, it decreases for vacancy-like defects (∼7), and it reaches a minimum for boundaries in graphite (∼3.5). This makes Raman Spectroscopy a powerful tool to fully characterize graphene.
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Nanomaterials (Basel)
                Nanomaterials (Basel)
                nanomaterials
                Nanomaterials
                MDPI
                2079-4991
                09 April 2021
                April 2021
                : 11
                : 4
                : 961
                Affiliations
                [1 ]Department of Civil Engineering, ISISE, University of Minho, 4800-058 Guimarães, Portugal; mohammadmehdi.abedi@ 123456gmail.com (M.A.); agc@ 123456civil.uminho.pt (A.G.C.)
                [2 ]Department of Mechanical Engineering, University of Minho, Campus de Azurém, 4800-058 Guimarães, Portugal
                Author notes
                Author information
                https://orcid.org/0000-0002-2920-9284
                https://orcid.org/0000-0003-3303-6563
                https://orcid.org/0000-0002-0103-2579
                Article
                nanomaterials-11-00961
                10.3390/nano11040961
                8069268
                90172e69-0ab5-4103-bb4a-ba34c3d1c95e
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 25 February 2021
                : 06 April 2021
                Categories
                Article

                self-sensing,stabilized sand,cnt/gnp,mechanical,microstructural,durability,piezoresistivity

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