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      A flexible solid-state electrolyte for wide-scale integration of rechargeable zinc–air batteries

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          Abstract

          Replacing liquid electrolytes with a versatile, solid-state membrane based on highly functionalized cellulose nanofibers allows for easy integration of rechargeable zinc–air into any bendable and wearable devices.

          Abstract

          Rechargeable zinc–air batteries, having high energy densities and cost-effectiveness, are important environmentally-benign energy storage solutions. Here we developed a facile strategy for fabricating a nanoporous alkaline-exchange electrolyte membrane from natural cellulose nanofibres, exhibiting high ionic-conductivity and water retention as well as high bending flexibility. These advantages render the membrane a promising solid-state electrolyte for rechargeable zinc–air batteries in lightweight and flexible electronic applications.

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          Most cited references43

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          What Are Batteries, Fuel Cells, and Supercapacitors?

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            Recent advances in zinc-air batteries.

            Zinc-air is a century-old battery technology but has attracted revived interest recently. With larger storage capacity at a fraction of the cost compared to lithium-ion, zinc-air batteries clearly represent one of the most viable future options to powering electric vehicles. However, some technical problems associated with them have yet to be resolved. In this review, we present the fundamentals, challenges and latest exciting advances related to zinc-air research. Detailed discussion will be organized around the individual components of the system - from zinc electrodes, electrolytes, and separators to air electrodes and oxygen electrocatalysts in sequential order for both primary and electrically/mechanically rechargeable types. The detrimental effect of CO2 on battery performance is also emphasized, and possible solutions summarized. Finally, other metal-air batteries are briefly overviewed and compared in favor of zinc-air.
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              Is Open Access

              Cellulose crystallinity index: measurement techniques and their impact on interpreting cellulase performance

              Although measurements of crystallinity index (CI) have a long history, it has been found that CI varies significantly depending on the choice of measurement method. In this study, four different techniques incorporating X-ray diffraction and solid-state 13C nuclear magnetic resonance (NMR) were compared using eight different cellulose preparations. We found that the simplest method, which is also the most widely used, and which involves measurement of just two heights in the X-ray diffractogram, produced significantly higher crystallinity values than did the other methods. Data in the literature for the cellulose preparation used (Avicel PH-101) support this observation. We believe that the alternative X-ray diffraction (XRD) and NMR methods presented here, which consider the contributions from amorphous and crystalline cellulose to the entire XRD and NMR spectra, provide a more accurate measure of the crystallinity of cellulose. Although celluloses having a high amorphous content are usually more easily digested by enzymes, it is unclear, based on studies published in the literature, whether CI actually provides a clear indication of the digestibility of a cellulose sample. Cellulose accessibility should be affected by crystallinity, but is also likely to be affected by several other parameters, such as lignin/hemicellulose contents and distribution, porosity, and particle size. Given the methodological dependency of cellulose CI values and the complex nature of cellulase interactions with amorphous and crystalline celluloses, we caution against trying to correlate relatively small changes in CI with changes in cellulose digestibility. In addition, the prediction of cellulase performance based on low levels of cellulose conversion may not include sufficient digestion of the crystalline component to be meaningful.
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                Author and article information

                Journal
                EESNBY
                Energy & Environmental Science
                Energy Environ. Sci.
                Royal Society of Chemistry (RSC)
                1754-5692
                1754-5706
                2016
                2016
                : 9
                : 2
                : 663-670
                Affiliations
                [1 ]Department of Chemical Engineering
                [2 ]Waterloo Institute for Nanotechnology
                [3 ]Waterloo Institute for Sustainable Energy
                [4 ]University of Waterloo
                [5 ]Waterloo
                [6 ]University of New Brunswick
                [7 ]Fredericton
                [8 ]Canada
                [9 ]College of Environmental Science and Engineering
                [10 ]Donghua University
                [11 ]Shanghai 201620
                [12 ]P. R. China
                Article
                10.1039/C5EE03404C
                8c232b46-2563-490f-bcff-f7cc42b56925
                © 2016
                History

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