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      Cyclic Deformation Behavior of A Heat-Treated Die-Cast Al-Mg-Si-Based Aluminum Alloy

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          Abstract

          The purpose of this investigation was to study the low-cycle fatigue (LCF) behavior of a newly developed high-pressure die-cast (HPDC) Al-5.5Mg-2.5Si-0.6Mn-0.2Fe (AlMgSiMnFe) alloy. The effect of heat-treatment in comparison with its as-cast counterpart was also identified. The layered (α-Al + Mg 2Si) eutectic structure plus a small amount of Al 8(Fe,Mn) 2Si phase in the as-cast condition became an in-situ Mg 2Si particulate-reinforced aluminum composite with spherical Mg 2Si particles uniformly distributed in the α-Al matrix after heat treatment. Due to the spheroidization of intermetallic phases including both Mg 2Si and Al 8(Fe,Mn) 2Si, the ductility and hardening capacity increased while the yield stress (YS) and ultimate tensile strength (UTS) decreased. Portevin–Le Chatelier effect (or serrated flow) was observed in both tensile stress–strain curves and initial hysteresis loops during cyclic deformation because of dynamic strain aging caused by strong dislocation–precipitate interactions. The alloy exhibited cyclic hardening in both as-cast and heat-treated conditions when the applied total strain amplitude was above 0.4%, below which cyclic stabilization was sustained. The heat-treated alloy displayed a larger plastic strain amplitude and a lower stress amplitude at a given total strain amplitude, demonstrating a superior fatigue resistance in the LCF regime. A simple equation based on the stress amplitude of the first and mid-life cycles ( ( Δ σ / 2 ) f i r s t , ( Δ σ / 2 ) m i d ) was proposed to characterize the degree of cyclic hardening/softening ( D): D = ± ( Δ σ / 2 ) m i d     ( Δ σ / 2 ) f i r s t ( Δ σ / 2 ) f i r s t , where the positive sign “+” represents cyclic hardening and the negative sign “−“ reflects cyclic softening.

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          Opportunities and challenges for a sustainable energy future.

          Access to clean, affordable and reliable energy has been a cornerstone of the world's increasing prosperity and economic growth since the beginning of the industrial revolution. Our use of energy in the twenty-first century must also be sustainable. Solar and water-based energy generation, and engineering of microbes to produce biofuels are a few examples of the alternatives. This Perspective puts these opportunities into a larger context by relating them to a number of aspects in the transportation and electricity generation sectors. It also provides a snapshot of the current energy landscape and discusses several research and development opportunities and pathways that could lead to a prosperous, sustainable and secure energy future for the world.
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            Impacts and mitigation of excess diesel-related NOx emissions in 11 major vehicle markets

            Vehicle emissions contribute to fine particulate matter (PM2.5) and tropospheric ozone air pollution, affecting human health, crop yields and climate worldwide. On-road diesel vehicles produce approximately 20 per cent of global anthropogenic emissions of nitrogen oxides (NOx), which are key PM2.5 and ozone precursors. Regulated NOx emission limits in leading markets have been progressively tightened, but current diesel vehicles emit far more NOx under real-world operating conditions than during laboratory certification testing. Here we show that across 11 markets, representing approximately 80 per cent of global diesel vehicle sales, nearly one-third of on-road heavy-duty diesel vehicle emissions and over half of on-road light-duty diesel vehicle emissions are in excess of certification limits. These excess emissions (totalling 4.6 million tons) are associated with about 38,000 PM2.5- and ozone-related premature deaths globally in 2015, including about 10 per cent of all ozone-related premature deaths in the 28 European Union member states. Heavy-duty vehicles are the dominant contributor to excess diesel NOx emissions and associated health impacts in almost all regions. Adopting and enforcing next-generation standards (more stringent than Euro 6/VI) could nearly eliminate real-world diesel-related NOx emissions in these markets, avoiding approximately 174,000 global PM2.5- and ozone-related premature deaths in 2040. Most of these benefits can be achieved by implementing Euro VI standards where they have not yet been adopted for heavy-duty vehicles.
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              Sustainable minerals and metals for a low-carbon future

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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                16 September 2020
                September 2020
                : 13
                : 18
                : 4115
                Affiliations
                [1 ]Department of Mechanical and Industrial Engineering, Ryerson University, 350 Victoria Street, Toronto, Ontario M5B 2K3, Canada; sohail@ 123456ryerson.ca (S.M.); shubham.vaishya09@ 123456gmail.com (S.G.)
                [2 ]Department of Metallurgical and Materials Engineering, National Institute of Technology, Tiruchirappalli 620015, India
                [3 ]State Key Laboratory of Metal Matrix Composites, School of Materials Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China; xqzeng@ 123456sjtu.edu.cn
                Author notes
                [* ]Correspondence: lidejiang@ 123456sjtu.edu.cn (D.L.); dchen@ 123456ryerson.ca (D.C.); Tel.: +86-(021)-5474-0838 (D.L.); +1-(416)-979-5000 (ext. 6487) (D.C.); Fax: +86-(021)-3420-2794 (D.L.); +1-(416)-979-5265 (D.C.)
                Author information
                https://orcid.org/0000-0002-9277-7727
                https://orcid.org/0000-0003-3420-3626
                Article
                materials-13-04115
                10.3390/ma13184115
                7560315
                32947967
                848e3161-69b2-4de1-af4e-b24477385d4c
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 23 August 2020
                : 14 September 2020
                Categories
                Article

                almgsimnfe alloy,heat treatment,low-cycle fatigue,cyclic hardening,serrated flow

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