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      Analytical methods for the measurement of polymerization kinetics and stresses of dental resin-based composites: A review

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          Abstract

          Resin-based composites are commonly used restorative materials in dentistry. Such tooth-colored restorations can adhere to the dental tissues. One drawback is that the polymerization shrinkage and induced stresses during the curing procedure is an inherent property of resin composite materials that might impair their performance. This review focuses on the significant developments of laboratory tools in the measurement of polymerization shrinkage and stresses of dental resin-based materials during polymerization. An electronic search of publications from January 1977 to July 2016 was made using ScienceDirect, PubMed, Medline, and Google Scholar databases. The search included only English-language articles. Only studies that performed laboratory methods to evaluate the amount of the polymerization shrinkage and/or stresses of dental resin-based materials during polymerization were selected. The results indicated that various techniques have been introduced with different mechanical/physical bases. Besides, there are factors that may contribute the differences between the various methods in measuring the amount of shrinkages and stresses of resin composites. The search for an ideal and standard apparatus for measuring shrinkage stress and volumetric polymerization shrinkage of resin-based materials in dentistry is still required. Researchers and clinicians must be aware of differences between analytical methods to make proper interpretation and indications of each technique relevant to a clinical situation.

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          Recent advances and developments in composite dental restorative materials.

          Composite dental restorations represent a unique class of biomaterials with severe restrictions on biocompatibility, curing behavior, esthetics, and ultimate material properties. These materials are presently limited by shrinkage and polymerization-induced shrinkage stress, limited toughness, the presence of unreacted monomer that remains following the polymerization, and several other factors. Fortunately, these materials have been the focus of a great deal of research in recent years with the goal of improving restoration performance by changing the initiation system, monomers, and fillers and their coupling agents, and by developing novel polymerization strategies. Here, we review the general characteristics of the polymerization reaction and recent approaches that have been taken to improve composite restorative performance.
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            Factors involved in the development of polymerization shrinkage stress in resin-composites: a systematic review.

            Polymerization shrinkage stress of resin-composite materials may have a negative impact on the clinical performance of bonded restorations. The purpose of this systematic review is to discuss the primary factors involved with polymerization shrinkage stress development. According to the current literature, polymerization stress of resin composites is determined by their volumetric shrinkage, viscoelastic behavior and by restrictions imposed to polymerization shrinkage. Therefore, the material's composition, its degree of conversion and reaction kinetics become aspects of interest, together with the confinement and compliance of the cavity preparation. Information provided in this review was based on original scientific research published in Dental, Chemistry and Biomaterials journals. Textbooks on Chemistry and Dental Materials were also referenced for basic concepts. Shrinkage stress development must be considered a multi-factorial phenomenon. Therefore, accessing the specific contribution of volumetric shrinkage, viscoelastic behavior, reaction kinetics and local conditions on stress magnitude seems impractical. Some of the restorative techniques aiming at stress reduction have limited applicability, because their efficiency varies depending upon the materials employed. Due to an intense research activity over the years, the understanding of this matter has increased remarkably, leading to the development of new restorative techniques and materials that may help minimize this problem.
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              Setting stress in composite resin in relation to configuration of the restoration.

              The setting stress in composite resins was studied as a function of restoration shape. The shape is described by the configuration factor, C, the ratio of the restoration's bonded to unbonded (free) surfaces. In an experimental set-up, the shape of the restoration was simulated by cylindrical forms of various dimensions. The shrinkage stress was measured continuously. It was shown that in most of the clinically relevant cavity configurations, the stress-relieving flow is not sufficient to preserve adhesion to dentin by dentin-bonding agents.
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                Author and article information

                Journal
                Dent Res J (Isfahan)
                Dent Res J (Isfahan)
                DRJ
                Dental Research Journal
                Medknow Publications & Media Pvt Ltd (India )
                1735-3327
                2008-0255
                Jul-Aug 2017
                : 14
                : 4
                : 225-240
                Affiliations
                [1 ]Department of Dental Biomaterials, School of Dentistry, Tehran University of Medical Sciences, Tehran, Iran
                [2 ]Department of Dental Biomaterials, School of Dentistry/Research Center for Science and Technology in Medicine, Tehran University of Medical Sciences, Tehran, Iran
                Author notes
                Address for correspondence: Dr. Tabassom Hooshmand, Department of Dental Biomaterials, School of Dentistry, Tehran University of Medical Sciences, North Kargar Avenue, Tehran 14174, Iran. E-mail: hoshmand@ 123456sina.tums.ac.ir
                Article
                DRJ-14-225
                10.4103/1735-3327.211628
                5553250
                7bb0a38a-bf44-405b-9da4-bc2bcf47c935
                Copyright: © 2017 Dental Research Journal

                This is an open access article distributed under the terms of the Creative Commons Attribution-NonCommercial-ShareAlike 3.0 License, which allows others to remix, tweak, and build upon the work non-commercially, as long as the author is credited and the new creations are licensed under the identical terms.

                History
                : November 2016
                : May 2017
                Categories
                Review Article

                Dentistry
                analytical procedure,polymerization,resin composite,shrinkage,stress
                Dentistry
                analytical procedure, polymerization, resin composite, shrinkage, stress

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