Na3V2(PO4)3 particles partly embedded in carbon nanofibers with superb kinetics for ultra-high power sodium ion batteries

Abstract

Na ₃V ₂(PO ₄) ₃ particles partly embedded in carbon nanofibers enabled fast electronic conduction as well as facile Na ion migration simultaneously. As a result, the composite showed excellent electrochemical properties as a cathode material for sodium ion batteries.

Abstract

We here describe the extraordinary performance of NASICON Na ₃V ₂(PO ₄) ₃-carbon nanofiber (NVP–CNF) composites with ultra-high power and excellent cycling performance. NVP–CNFs are composed of CNFs at the center part and partly embedded NVP nanoparticles in the shell. We first report this unique morphology of NVP–CNFs for the electrode material of secondary batteries as well as for general energy conversion materials. Our NVP–CNFs show not only a high discharge capacity of ∼88.9 mA h g ⁻¹ even at a high current density of 50 C but also ∼93% cyclic retention property after 300 cycles at 1 C. The superb kinetics and excellent cycling performance of the NVP–CNFs are attributed to the facile migration of Na ions through the partly exposed regions of NVP nanoparticles that are directly in contact with an electrolyte as well as the fast electron transfer along the conducting CNF pathways.