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      Versatile Gas-Transfer Membrane in Water and Wastewater Treatment: Principles, Opportunities, and Challenges

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          Abstract

          Technologies using liquid-transfer membranes, such as microfiltration, ultrafiltration, and reverse osmosis, have been widely applied in water and wastewater treatment. In the last few decades, gas-transfer membranes have been introduced in various fields to facilitate mass transfer, in which gaseous compounds permeate through membrane pores driven by gradients in chemical concentration or potential. A notable knowledge gap exists among researchers working on these emerging gas-transfer membranes as they approach this subject from different angles and areas of expertise (e.g., material science versus microbiology). This review explores the versatile applications of gas-transfer membranes in water and wastewater treatment, categorizing them into three primary types according to the function of membranes: water vapor transferring, gaseous reactant supplying, and gaseous compound extraction. For each type, the principles, evolution, and potential for further development were elaborated. Moreover, this review highlights the potential knowledge transfer between different fields, as insights from one type of gas-transfer membrane could potentially benefit another. Despite their technical innovations, these processes still face challenges in practical operation, such as membrane fouling and wetting. We advocate for research focusing on more practical and sustainable membranes and careful consideration of these emerging membrane technologies in specific scenarios. The current practicality and maturity of these emerging processes in water and wastewater treatment are described by the Technology Readiness Level (TRL) framework. Particularly, ongoing fundamental progress in membranes and engineering is expected to continue fueling the future development of these technologies.

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          Effective ion sieving with Ti3C2Tx MXene membranes for production of drinking water from seawater

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            Metal–organic frameworks based membranes for liquid separation

            This Tutorial Review highlights the achievements in the rational design and the latest applications of MOF-based membranes in liquid separation. Metal–organic frameworks (MOFs) represent a fascinating class of solid crystalline materials which can be self-assembled in a straightforward manner by the coordination of metal ions or clusters with organic ligands. Owing to their intrinsic porous characteristics, unique chemical versatility and abundant functionalities, MOFs have received substantial attention for diverse industrial applications, including membrane separation. Exciting research activities ranging from fabrication strategies to separation applications of MOF-based membranes have appeared. Inspired by the marvelous achievements of MOF-based membranes in gas separations, liquid separations are also being explored for the purpose of constructing continuous MOFs membranes or MOF-based mixed matrix membranes. Although these are in an emerging stage of vigorous development, most efforts are directed towards improving the liquid separation efficiency with well-designed MOF-based membranes. Therefore, as an increasing trend in membrane separation, the field of MOF-based membranes for liquid separation is highlighted in this review. The criteria for judicious selection of MOFs in fabricating MOF-based membranes are given. Special attention is paid to rational design strategies for MOF-based membranes, along with the latest application progress in the area of liquid separations, such as pervaporation, water treatment, and organic solvent nanofiltration. Moreover, some attractive dual-function applications of MOF-based membranes in the removal of micropollutants, degradation, and antibacterial activity are also reviewed. Finally, we define the remaining challenges and future opportunities in this field. This Tutorial Review provides an overview and outlook for MOF-based membranes for liquid separations. Further development of MOF-based membranes for liquid separation must consider the demands of strict separation standards and environmental safety for industrial application.
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              The Global Rise of Zero Liquid Discharge for Wastewater Management: Drivers, Technologies, and Future Directions.

              Zero liquid discharge (ZLD)-a wastewater management strategy that eliminates liquid waste and maximizes water usage efficiency - has attracted renewed interest worldwide in recent years. Although implementation of ZLD reduces water pollution and augments water supply, the technology is constrained by high cost and intensive energy consumption. In this critical review, we discuss the drivers, incentives, technologies, and environmental impacts of ZLD. Within this framework, the global applications of ZLD in the United States and emerging economies such as China and India are examined. We highlight the evolution of ZLD from thermal- to membrane-based processes, and analyze the advantages and limitations of existing and emerging ZLD technologies. The potential environmental impacts of ZLD, notably greenhouse gas emission and generation of solid waste, are discussed and the prospects of ZLD technologies and research needs are highlighted.
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                Author and article information

                Journal
                ACS Environ Au
                ACS Environ Au
                vg
                aeacc4
                ACS Environmental Au
                American Chemical Society
                2694-2518
                29 January 2025
                19 March 2025
                : 5
                : 2
                : 152-164
                Affiliations
                [1]Department of Civil and Environmental Engineering, The Hong Kong Polytechnic University , Hong Kong 999077, PR China
                Author notes
                Author information
                https://orcid.org/0000-0001-7673-747X
                Article
                10.1021/acsenvironau.4c00134
                11926753
                761f0f80-70a2-4883-a1f1-e5822a636ac6
                © 2025 The Authors. Published by American Chemical Society

                Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works ( https://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 28 November 2024
                : 15 January 2025
                : 15 January 2025
                Funding
                Funded by: Australian Research Council, doi 10.13039/501100000923;
                Award ID: DE220101310
                Funded by: Research Grants Council, University Grants Committee, doi 10.13039/501100002920;
                Award ID: PolyU 25238324
                Categories
                Review
                Custom metadata
                vg4c00134
                vg4c00134

                gas-transfer membrane,membrane distillation,pervaporation,membrane biofilm reactor,mbfr,membrane-aerated biofilm reactor,mabr,membrane contactor,membrane gas stripping,mgs,membrane gas absorption,mga

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