Changes in soil moisture and soil temperature result from the combined effects of several environmental factors. Scientific determination of the response characteristics of soil moisture and soil temperature to environmental factors is critical for adjusting the sloping land use structure and improving the ecological environment in China’s loess hilly region. Soybean sloping fields, maize terraced fields, jujube orchards, and grasslands in the loess hilly region were selected as the research areas. The change in characteristics of soil moisture and soil temperature, as well as their interactions and statistical relationships with meteorological factors, were analyzed using continuously measured soil moisture, soil temperature, and meteorological factors. The results revealed that air temperature and humidity were the main controlling factors affecting soil moisture changes in the 0–60 cm soil layer of soybean sloping fields and grasslands in the normal precipitation year (2014) and the dry year (2015). Humidity and wind speed were the main meteorological factors affecting soil moisture changes in the maize terraced field. Air temperature had a significant negative effect on soil moisture in the jujube orchard. Soil moisture and soil temperature were all negatively correlated under the four sloping land use types. In normal precipitation years, atmospheric humidity had the greatest direct and comprehensive effect on soil moisture in soybean sloping fields, maize terraced fields, and grasslands; soil temperature had a relatively large impact on soil moisture in jujube orchards. The direct and comprehensive effects of soil temperature on soil moisture under all sloping land use types were the largest and most negative in the dry year. Air temperature had a high correlation with soil temperature in the 0–60 cm soil layer under the four sloping land use types, and the grey relational grade decreased as the soil layer deepened. The coefficient of determination between the 0–20 cm soil temperature and air temperature in the maize terraced field was low, indicating a weak response to air temperature. The above findings can serve as a scientific foundation for optimizing sloping land use structures and maximizing the efficient and sustainable utilization of sloping land resources in China’s loess hilly region.