We have measured the Faraday rotation of 62 extra-galactic background sources in 58 fields using the CSIRO Australia Telescope Compact Array (ATCA) with a frequency range of 1.1–3.1 GHz with 2048 channels. Our sources cover a region $\sim 12\, \times 12\, \mathrm{deg^{ 2}}\((∼1 kpc) around the Galactic Centre region. We show that the Galactic Plane for |l| < 10° exhibits large Rotation Measures (RMs) with a maximum |RM| of \)1691.2 \pm 4.9\, \mathrm{rad}\, \mathrm{m}^{-2}\(and a mean \)|\mathrm{RM}| = 219 \pm 42\, \mathrm{rad}\, \mathrm{m}^{-2}$. The RMs decrease in magnitude with increasing projected distance from the Galactic Plane, broadly consistent with previous findings. We find an unusually high fraction (95 per cent) of the sources show Faraday complexity consistent with multiple Faraday components. We attribute the presences of multiple Faraday rotating screens with widely separated Faraday depths to small-scale turbulent RM structure in the Galactic Centre region. The second-order structure function of the RM in the Galactic Centre displays a line with a gradient of zero for angular separations spanning 0.83°–11° (∼120–1500 pc), which is expected for scales larger than the outer scale (or driving scale) of magneto-ionic turbulence. We place an upper limit on any break in the SF gradient of 66 arcsec, corresponding to an inferred upper limit to the outer scale of turbulence in the inner 1 kpc of the Galactic Centre of 3 pc. We propose stellar feedback as the probable driver of this small-scale turbulence.