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      N-(1,5-Dimethyl-3-oxo-2-phenyl-2,3-di­hydro-1 H-pyrazol-4-yl)-2-(4-nitro­phen­yl)acetamide

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          Abstract

          In the title compound, C 19H 18N 4O 4, the nitro­phenyl and phenyl rings are twisted by 67.0 (6) and 37.4 (4)°, respectively, with respect to the pyrazole ring plane [maximum deviation = 0.0042 (16) Å]. The dihedral angle between the mean planes of the phenyl rings is 59.3 (3)°. The amide group, with a C—N—C—C torsion angle of 177.54 (13)°, is twisted away from the plane of the pyrazole ring in an anti­periplanar conformation. In the crystal, N—H⋯O hydrogen bonds involving the carbonyl group on the pyrazole ring and the amide group, together with weak C—H⋯O inter­actions forming R 2 2(10) graph-set motifs, link the mol­ecules into chains along [100]. Additional weak C—H⋯O inter­actions involving the nitro­phenyl rings further link the mol­ecules along [001], also forming R 2 2(10) graph-set motifs, thereby generating (010) layers.

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          Journal
          Acta Crystallogr Sect E Struct Rep Online
          Acta Crystallogr Sect E Struct Rep Online
          Acta Cryst. E
          Acta Crystallographica Section E: Structure Reports Online
          International Union of Crystallography
          1600-5368
          01 June 2014
          03 May 2014
          03 May 2014
          : 70
          : Pt 6 ( publisher-idID: e140600 )
          : o636-o637
          Affiliations
          [a ]Department of Studies in Chemistry, University of Mysore, Manasagangotri, Mysore 570 006, India
          [b ]Department of Chemistry, Keene State College, 229 Main Street, Keene, NH 03435-2001, USA
          [c ]Department of Studies in Chemistry, Mangalore University, Mangalagangotri 574 199, India
          [d ]Materials Science Center, University of Mysore, Vijyana Bhavan Building, Manasagangothri, Mysore 570 006, India
          Author notes
          Correspondence e-mail: jjasinski@ 123456keene.edu
          Article
          hg5393 ACSEBH S1600536814009738
          10.1107/S1600536814009738
          4051092
          7196277d-649f-4a0a-8ce9-eecf0d06dc96
          © Kaur et al. 2014

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          : 26 April 2014
          : 30 April 2014
          Categories
          Organic Papers

          Materials characterization
          Materials characterization

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