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      Tetra­kis(1,1,1-trifluoro­acetyl­acetonato-κ 2 O, O′)zirconium(IV) toluene solvate

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          Abstract

          In the title compound, [Zr(C 5H 4F 3O 2) 4]·C 7H 8, the Zr atom is in a square-anti­prismatic coordination geometry that comprises four O, O′-bidentate trifluoro­acetyl­acetonate ligands. The O—Zr—O bite angles of the acetonate ligands range from 75.27 (5) to 75.41 (5)°. The Zr atom is located on a twofold rotation axis.

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          Author and article information

          Journal
          Journal ID (nlm-ta): Acta Crystallogr Sect E Struct Rep Online
          Journal ID (publisher-id): Acta Cryst. E
          Title: Acta Crystallographica Section E: Structure Reports Online
          Publisher: International Union of Crystallography
          ISSN (Electronic): 1600-5368
          Publication date Collection: 01 June 2008
          Publication date (Electronic): 21 May 2008
          Publication date PMC-release: 21 May 2008
          Volume: 64
          Issue: Pt 6 ( publisher-idID: e080600 )
          Page: m827
          Affiliations
          [a ]Department of Chemistry, University of the Free State, PO Box 339, Bloemfontein 9300, South Africa
          Author notes
          Correspondence e-mail: steylg.sci@ 123456ufs.ac.za
          Article
          Publisher ID: ng2456 Coden ID: ACSEBH Publisher Item ID: S1600536808014499
          DOI: 10.1107/S1600536808014499
          PMC ID: 2961572
          PubMed ID: 21202509
          SO-VID: 70daacf5-c061-4938-a51e-d0d8d0d00aea
          Copyright © © Steyn et al. 2008
          License:

          This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.

          History
          Date received : 12 May 2008
          Date accepted : 14 May 2008
          Categories
          Subject: Metal-Organic Papers

          ScienceOpen disciplines: Materials characterization
          Data availability:
          ScienceOpen disciplines: Materials characterization

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