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      Piezoelectric Materials: Properties, Advancements, and Design Strategies for High-Temperature Applications

      , ,
      Nanomaterials
      MDPI AG

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          Abstract

          Piezoelectronics, as an efficient approach for energy conversion and sensing, have a far-reaching influence on energy harvesting, precise instruments, sensing, health monitoring and so on. A majority of the previous works on piezoelectronics concentrated on the materials that are applied at close to room temperatures. However, there is inadequate research on the materials for high-temperature piezoelectric applications, yet they also have important applications in the critical equipment of aeroengines and nuclear reactors in harsh and high-temperature conditions. In this review, we briefly introduce fundamental knowledge about the piezoelectric effect, and emphatically elucidate high-temperature piezoelectrics, involving: the typical piezoelectric materials operated in high temperatures, and the applications, limiting factors, prospects and challenges of piezoelectricity at high temperatures.

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          Most cited references152

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          Organometal halide perovskites as visible-light sensitizers for photovoltaic cells.

          Two organolead halide perovskite nanocrystals, CH(3)NH(3)PbBr(3) and CH(3)NH(3)PbI(3), were found to efficiently sensitize TiO(2) for visible-light conversion in photoelectrochemical cells. When self-assembled on mesoporous TiO(2) films, the nanocrystalline perovskites exhibit strong band-gap absorptions as semiconductors. The CH(3)NH(3)PbI(3)-based photocell with spectral sensitivity of up to 800 nm yielded a solar energy conversion efficiency of 3.8%. The CH(3)NH(3)PbBr(3)-based cell showed a high photovoltage of 0.96 V with an external quantum conversion efficiency of 65%.
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            Compositional engineering of perovskite materials for high-performance solar cells.

            Of the many materials and methodologies aimed at producing low-cost, efficient photovoltaic cells, inorganic-organic lead halide perovskite materials appear particularly promising for next-generation solar devices owing to their high power conversion efficiency. The highest efficiencies reported for perovskite solar cells so far have been obtained mainly with methylammonium lead halide materials. Here we combine the promising-owing to its comparatively narrow bandgap-but relatively unstable formamidinium lead iodide (FAPbI3) with methylammonium lead bromide (MAPbBr3) as the light-harvesting unit in a bilayer solar-cell architecture. We investigated phase stability, morphology of the perovskite layer, hysteresis in current-voltage characteristics, and overall performance as a function of chemical composition. Our results show that incorporation of MAPbBr3 into FAPbI3 stabilizes the perovskite phase of FAPbI3 and improves the power conversion efficiency of the solar cell to more than 18 per cent under a standard illumination of 100 milliwatts per square centimetre. These findings further emphasize the versatility and performance potential of inorganic-organic lead halide perovskite materials for photovoltaic applications.
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              Piezoelectric nanogenerators based on zinc oxide nanowire arrays.

              We have converted nanoscale mechanical energy into electrical energy by means of piezoelectric zinc oxide nanowire (NW) arrays. The aligned NWs are deflected with a conductive atomic force microscope tip in contact mode. The coupling of piezoelectric and semiconducting properties in zinc oxide creates a strain field and charge separation across the NW as a result of its bending. The rectifying characteristic of the Schottky barrier formed between the metal tip and the NW leads to electrical current generation. The efficiency of the NW-based piezoelectric power generator is estimated to be 17 to 30%. This approach has the potential of converting mechanical, vibrational, and/or hydraulic energy into electricity for powering nanodevices.
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                Author and article information

                Journal
                NANOKO
                Nanomaterials
                Nanomaterials
                MDPI AG
                2079-4991
                April 2022
                April 01 2022
                : 12
                : 7
                : 1171
                Article
                10.3390/nano12071171
                6fc419ea-5f86-431c-8207-1ba226587ec4
                © 2022

                https://creativecommons.org/licenses/by/4.0/

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