Fe-based metal organic frameworks (Fe-MOFs) for organic pollutants removal via photo-Fenton: A review

Du, Chunyan; Zhang, Yin; Zhang, Zhuo; Zhou, Lu; Yu, Guanlong; Wen, Xiaofeng; Chi, Tianying; Wang, Guoliang; Su, Yihai; Deng, Fangfang; Lv, Yinchu; Zhu, Hao

doi:10.1016/j.cej.2021.133932

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Fe-based metal organic frameworks (Fe-MOFs) for organic pollutants removal via photo-Fenton: A review

Author(s): Chunyan Du , Yin Zhang , Zhuo Zhang , Lu Zhou , Guanlong Yu , Xiaofeng Wen , Tianying Chi , Guoliang Wang , Yihai Su , Fangfang Deng , Yinchu Lv , Hao Zhu

Publication date Created: March 2022

Publication date (Print): March 2022

Journal: Chemical Engineering Journal

Publisher: Elsevier BV

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A chromium terephthalate-based solid with unusually large pore volumes and surface area.

G Férey, C Mellot-Draznieks, C. Serre … (2005)

We combined targeted chemistry and computational design to create a crystal structure for porous chromium terephthalate, MIL-101, with very large pore sizes and surface area. Its zeotype cubic structure has a giant cell volume (approximately 702,000 cubic angstroms), a hierarchy of extra-large pore sizes (approximately 30 to 34 angstroms), and a Langmuir surface area for N2 of approximately 5900 +/- 300 square meters per gram. Beside the usual properties of porous compounds, this solid has potential as a nanomold for monodisperse nanomaterials, as illustrated here by the incorporation of Keggin polyanions within the cages.