Manipulating the ion-transfer kinetics and interface stability for high-performance zinc metal anodes

Abstract

We report a new class of Zn anodes modified by a three-dimensional nanoporous ZnO architecture (Zn@ZnO-3D), which can accelerate the kinetics of Zn ²⁺ transfer and deposition, inhibit dendrite growth, and reduce the side-reactions.

Abstract

The zinc metal is recognized as one of the most promising anodes for Zn-based batteries in an energy-storage system. However, the deposition and transfer of bivalent Zn ²⁺ into the host structure suffer from sluggish kinetics accompanying the side-reactions at the interface. Herein, we report a new class of Zn anodes modified by a three-dimensional (3D) nanoporous ZnO architecture coating on a Zn plate (designated as Zn@ZnO-3D) prepared by in situ Zn(OH) ₄ ²⁻ deposition onto the surface. This novel structure has been proven to accelerate the kinetics of Zn ²⁺ transfer and deposition via the electrostatic attraction toward Zn ²⁺ rather than the hydrated one in the electrical double layer. As a consequence, it achieves an average 99.55% Zn utilization and long-time stability for 1000 cycles. Meanwhile, the Zn@ZnO-3D/MnO ₂ cell shows no capacity fading after 500 cycles at 0.5 A g ⁻¹ with a specific capacity of 212.9 mA h g ⁻¹. We believe that the mechanistic insight into the kinetics and thermodynamic properties of the Zn metal and the understanding of structure–interface–function relationships are very useful for other metal anodes in aqueous systems.