Graphdiyne@Janus Magnetite for Photocatalytic Nitrogen Fixation

Nitrogen is fundamental to all of life and to many industrial processes. Nitrogen in its various oxidation states comprises the global nitrogen cycle, with the change between forms being redox reactions involving electrons and protons. The interchange of nitrogen oxidation states constitutes some of the most important industrial processes, with the energy for these processes being provided largely by fossil fuel. A key goal of research in the field of nitrogen chemistry is to minimize the use of fossil fuels by developing more efficient heterogeneous, homogeneous, or biological catalysts, or by inventing new energy-efficient processes that rely on catalysts. These approaches, as well as the challenges involved, are discussed in this review. This review article reports on the current state of the field of nitrogen activation chemistry and discusses future directions.

We have demonstrated a methodology to generate large area graphdiyne films with 3.61 cm(2) on the surface of copper via a cross-coupling reaction using hexaethynylbenzene. The device based on graphdiyne films for measurement of electrical property is fabricated and shows conductivity of 2.516 x 10(-4) S m(-1) indicating a semiconductor property.

Even though the well-established Haber-Bosch process has been the major artificial way to "fertilize" the earth, its energy-intensive nature has been motivating people to learn from nitrogenase, which can fix atmospheric N2 to NH3 in vivo under mild conditions with its precisely arranged proteins. Here we demonstrate that efficient fixation of N2 to NH3 can proceed under room temperature and atmospheric pressure in water using visible light illuminated BiOBr nanosheets of oxygen vacancies in the absence of any organic scavengers and precious-metal cocatalysts. The designed catalytic oxygen vacancies of BiOBr nanosheets on the exposed {001} facets, with the availability of localized electrons for π-back-donation, have the ability to activate the adsorbed N2, which can thus be efficiently reduced to NH3 by the interfacial electrons transferred from the excited BiOBr nanosheets. This study might open up a new vista to fix atmospheric N2 to NH3 through the less energy-demanding photochemical process.