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      Determination of rock properties by low-frequency AC electrokinetics

      , ,
      Journal of Geophysical Research: Solid Earth
      American Geophysical Union (AGU)

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          Theory of dynamic permeability and tortuosity in fluid-saturated porous media

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            Quantitative prediction of permeability in porous rock

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              Is Open Access

              Steric Effects in Electrolytes: A Modified Poisson-Boltzmann Equation

              The adsorption of large ions from solution to a charged surface is investigated theoretically. A generalized Poisson--Boltzmann equation, which takes into account the finite size of the ions is presented. We obtain analytical expressions for the electrostatic potential and ion concentrations at the surface, leading to a modified Grahame equation. At high surface charge densities the ionic concentration saturates to its maximum value. Our results are in agreement with recent experiments.
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                Author and article information

                Journal
                Journal of Geophysical Research: Solid Earth
                J. Geophys. Res.
                American Geophysical Union (AGU)
                01480227
                December 10 1999
                December 10 1999
                : 104
                : B12
                : 29485-29508
                Article
                10.1029/1999JB900277
                60d1636b-7a6a-4bbb-8dd4-d410beeb3b66
                © 1999

                http://doi.wiley.com/10.1002/tdm_license_1.1

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