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      Research progress of EMOFs-based burning rate catalysts for solid propellants

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          Abstract

          Energetic Metal Organic Frameworks (EMOFs) have been a hotspot of research on solid propellants in recent years. In this paper, research on the application of EMOFs-based burning rate catalysts in solid propellants was reviewed and the development trend of these catalysts was explored. The catalysts analyzed included monometallic organic frameworks-based energetic burning rate catalysts, bimetallic multifunctional energetic burning rate catalysts, carbon-supported EMOFs burning rate catalysts, and catalysts that can be used in conjunction with EMOFs. The review suggest that monometallic organic frameworks-based burning rate catalysts have relatively simple catalytic effects, and adding metal salts can improve their catalytic effect. Bimetallic multifunctional energetic burning rate catalysts have excellent catalytic performance and the potential for broad application. The investigation of carbon-supported EMOFs burning rate catalysts is still at a preliminary stage, but their preparation and application have become a research focus in the burning rate catalyst field. The application of catalysts that can be compounded with EMOFs should be promoted. Finally, environmental protection, high energy and low sensitivity, nanometerization, multifunctional compounding and solvent-free are proposed as key directions of future research. This study aims to provide a reference for the application of energetic organic burning rate catalysts in solid propellants.

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          3D energetic metal-organic frameworks: synthesis and properties of high energy materials.

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            Highly energetic compositions based on functionalized carbon nanomaterials.

            In recent years, research in the field of carbon nanomaterials (CNMs), such as fullerenes, expanded graphite (EG), carbon nanotubes (CNTs), graphene, and graphene oxide (GO), has been widely used in energy storage, electronics, catalysts, and biomaterials, as well as medical applications. Regarding energy storage, one of the most important research directions is the development of CNMs as carriers of energetic components by coating or encapsulation, thus forming safer advanced nanostructures with better performances. Moreover, some CNMs can also be functionalized to become energetic additives. This review article covers updated preparation methods for the aforementioned CNMs, with a more specific orientation towards the use of these nanomaterials in energetic compositions. The effects of these functionalized CNMs on thermal decomposition, ignition, combustion and the reactivity properties of energetic compositions are significant and are discussed in detail. It has been shown that the use of functionalized CNMs in energetic compositions greatly improves their combustion performances, thermal stability and sensitivity. In particular, functionalized fullerenes, CNTs and GO are the most appropriate candidate components in nanothermites, solid propellants and gas generators, due to their superior catalytic properties as well as facile preparation methods.
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              Synthesis and reactions of 1,1-diamino-2,2-dinitroethylene

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                Author and article information

                Contributors
                Journal
                Front Chem
                Front Chem
                Front. Chem.
                Frontiers in Chemistry
                Frontiers Media S.A.
                2296-2646
                13 October 2022
                2022
                : 10
                : 1032163
                Affiliations
                Xi’an Modern Chemistry Research Institute , Xi’an, Shaanxi, China
                Author notes

                Edited by: Paul Raithby, University of Bath, United Kingdom

                Reviewed by: Jiongpeng Zhao, Tianjin University of Technology, China

                Yang Ji-Min, Linyi University, China

                Ahmed Fouzi Tarchoun, Ecole Militaire Polytechnique (EMP), Algeria

                *Correspondence: Bojun Tan, tanbj204@ 123456163.com ; Ning Liu, flackliu@ 123456sina.com

                This article was submitted to Inorganic Chemistry, a section of the journal Frontiers in Chemistry

                Article
                1032163
                10.3389/fchem.2022.1032163
                9608550
                36311438
                5a3895ae-ea8d-4c79-8237-b555e9674293
                Copyright © 2022 Tan, Yang, Dou, Duan, Lu and Liu.

                This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.

                History
                : 30 August 2022
                : 20 September 2022
                Funding
                Funded by: National Natural Science Foundation of China , doi 10.13039/501100001809;
                Categories
                Chemistry
                Review

                solid propellant,energetic metal organic frameworks (emofs),energetic burning rate catalysts,environmental protection,high energy and low sensitivity,nanometerization,multifunctional compounding

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