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      Electrochemical Impedance Spectroscopy Based on the State of Health Estimation for Lithium-Ion Batteries

      , , , ,
      Energies
      MDPI AG

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          Abstract

          The state of health (SOH) is critical to the efficient and reliable use of lithium-ion batteries (LIBs). Recently, the SOH estimation method based on electrochemical impedance spectroscopy (EIS) has been proven effective. In response to different practical applications, two models for SOH estimation are proposed in this paper. Aiming at based on the equivalent circuit model (ECM) method, a variety of ECMs are proposed. Used EIS to predict the ECM, the results show that the improved method ensures the correctness of the ECM and improves the estimation results of SOH. Aiming at a data-driven algorithm, proposes a convolution neural network (CNN) to process EIS data which can not only extract the key points but also simplifies the complexity of manual feature extraction. The bidirectional long short-term memory (BiLSTM) model was used for serial regression prediction. Moreover, the improved Particle Swarm Optimization (IPSO) algorithm is proposed to optimize the model. Comparing the improved model (IPSO-CNN-BiLSTM) with the traditional PSO-CNN-BiLSTM, CNN-BiLSTM and LSTM models, the prediction results are improved by 13.6%, 93.75% and 94.8%, respectively. Besides that, the two proposed methods are 27% and 35% better than the existing gaussion process regression (GPR) model, which indicates that the proposed improved methods are more flexible for SOH estimation with higher precision.

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          Most cited references57

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          Degradation diagnostics for lithium ion cells

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            Synthesize battery degradation modes via a diagnostic and prognostic model

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              Identifying degradation patterns of lithium ion batteries from impedance spectroscopy using machine learning

              Forecasting the state of health and remaining useful life of Li-ion batteries is an unsolved challenge that limits technologies such as consumer electronics and electric vehicles. Here, we build an accurate battery forecasting system by combining electrochemical impedance spectroscopy (EIS)—a real-time, non-invasive and information-rich measurement that is hitherto underused in battery diagnosis—with Gaussian process machine learning. Over 20,000 EIS spectra of commercial Li-ion batteries are collected at different states of health, states of charge and temperatures—the largest dataset to our knowledge of its kind. Our Gaussian process model takes the entire spectrum as input, without further feature engineering, and automatically determines which spectral features predict degradation. Our model accurately predicts the remaining useful life, even without complete knowledge of past operating conditions of the battery. Our results demonstrate the value of EIS signals in battery management systems.
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                Author and article information

                Contributors
                Journal
                ENERGA
                Energies
                Energies
                MDPI AG
                1996-1073
                September 2022
                September 13 2022
                : 15
                : 18
                : 6665
                Article
                10.3390/en15186665
                58fdc056-38e4-4a07-aa77-158d42c6e9a9
                © 2022

                https://creativecommons.org/licenses/by/4.0/

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