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      3D printing of conducting polymers

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          Abstract

          Conducting polymers are promising material candidates in diverse applications including energy storage, flexible electronics, and bioelectronics. However, the fabrication of conducting polymers has mostly relied on conventional approaches such as ink-jet printing, screen printing, and electron-beam lithography, whose limitations have hampered rapid innovations and broad applications of conducting polymers. Here we introduce a high-performance 3D printable conducting polymer ink based on poly(3,4-ethylenedioxythiophene):polystyrene sulfonate (PEDOT:PSS) for 3D printing of conducting polymers. The resultant superior printability enables facile fabrication of conducting polymers into high resolution and high aspect ratio microstructures, which can be integrated with other materials such as insulating elastomers via multi-material 3D printing. The 3D-printed conducting polymers can also be converted into highly conductive and soft hydrogel microstructures. We further demonstrate fast and streamlined fabrications of various conducting polymer devices, such as a soft neural probe capable of in vivo single-unit recording.

          Abstract

          Conducting polymers are promising materials for diverse applications but the fabrication of conducting polymers mostly relies on conventional fabrication techniques. Here the authors introduce a high performance 3D printable conducting polymer ink to take full advantage of advanced 3D printing.

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          Most cited references34

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          Printing ferromagnetic domains for untethered fast-transforming soft materials

          Soft materials capable of transforming between three-dimensional (3D) shapes in response to stimuli such as light, heat, solvent, electric and magnetic fields have applications in diverse areas such as flexible electronics1,2, soft robotics3,4 and biomedicine5-7. In particular, magnetic fields offer a safe and effective manipulation method for biomedical applications, which typically require remote actuation in enclosed and confined spaces8-10. With advances in magnetic field control 11 , magnetically responsive soft materials have also evolved from embedding discrete magnets 12 or incorporating magnetic particles 13 into soft compounds to generating nonuniform magnetization profiles in polymeric sheets14,15. Here we report 3D printing of programmed ferromagnetic domains in soft materials that enable fast transformations between complex 3D shapes via magnetic actuation. Our approach is based on direct ink writing 16 of an elastomer composite containing ferromagnetic microparticles. By applying a magnetic field to the dispensing nozzle while printing 17 , we reorient particles along the applied field to impart patterned magnetic polarity to printed filaments. This method allows us to program ferromagnetic domains in complex 3D-printed soft materials, enabling a set of previously inaccessible modes of transformation, such as remotely controlled auxetic behaviours of mechanical metamaterials with negative Poisson's ratios. The actuation speed and power density of our printed soft materials with programmed ferromagnetic domains are orders of magnitude greater than existing 3D-printed active materials. We further demonstrate diverse functions derived from complex shape changes, including reconfigurable soft electronics, a mechanical metamaterial that can jump and a soft robot that crawls, rolls, catches fast-moving objects and transports a pharmaceutical dose.
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            High-Resolution Inkjet Printing of All-Polymer Transistor Circuits

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              The rise of plastic bioelectronics.

              Plastic bioelectronics is a research field that takes advantage of the inherent properties of polymers and soft organic electronics for applications at the interface of biology and electronics. The resulting electronic materials and devices are soft, stretchable and mechanically conformable, which are important qualities for interacting with biological systems in both wearable and implantable devices. Work is currently aimed at improving these devices with a view to making the electronic-biological interface as seamless as possible.
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                Author and article information

                Contributors
                zhaox@mit.edu
                Journal
                Nat Commun
                Nat Commun
                Nature Communications
                Nature Publishing Group UK (London )
                2041-1723
                30 March 2020
                30 March 2020
                2020
                : 11
                : 1604
                Affiliations
                [1 ]ISNI 0000 0001 2341 2786, GRID grid.116068.8, Department of Mechanical Engineering, , Massachusetts Institute of Technology, ; Cambridge, MA 02139 USA
                [2 ]GRID grid.411864.e, Flexible Electronics Innovation Institute, , Jiangxi Science and Technology Normal University, ; Nanchang, 330013 China
                [3 ]GRID grid.411864.e, School of Pharmacy, , Jiangxi Science and Technology Normal University, ; Nanchang, 330013 China
                [4 ]ISNI 0000 0001 2341 2786, GRID grid.116068.8, Department of Civil and Environmental Engineering, , Massachusetts Institute of Technology, ; Cambridge, 02139 USA
                [5 ]ISNI 0000 0004 1759 700X, GRID grid.13402.34, Department of Neurobiology, Key Laboratory of Medical Neurobiology of the Ministry of Health of China, Collaborative Innovation Center for Brain Science, , Zhejiang University of Medicine, Hangzhou, ; Zhejiang, 310058 China
                Author information
                http://orcid.org/0000-0003-1710-9750
                http://orcid.org/0000-0003-4663-4706
                http://orcid.org/0000-0001-5387-6186
                Article
                15316
                10.1038/s41467-020-15316-7
                7105462
                32231216
                560a9e05-301d-4e8b-acd9-fd61e7b35d01
                © The Author(s) 2020

                Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 30 July 2019
                : 21 February 2020
                Categories
                Article
                Custom metadata
                © The Author(s) 2020

                Uncategorized
                mechanical engineering,electronic devices,gels and hydrogels
                Uncategorized
                mechanical engineering, electronic devices, gels and hydrogels

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