Cobalt-Catalyzed Trifluoromethylation-Peroxidation of Unactivated Alkenes with Sodium Trifluoromethanesulfinate and Hydroperoxide.

There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

Abstract

Disclosed herein is an unprecedented cobalt-catalyzed trifluoromethylation-peroxidation of unactivated alkenes. In this process the hydroperoxide acts as a radical initiator as well as a coupling partner. The cheap and readily available sodium trifluoromethanesulfinate serves as the CF3 source in the reaction. Various alkenes are transformed into vicinal trifluoromethyl-peroxide compounds in moderate to good yields.

Related collections

Author and article information

Journal

Journal ID (iso-abbrev): Org Lett

Title: Organic letters

Publisher: American Chemical Society (ACS)

ISSN (Electronic): 1523-7052

ISSN (Print): 1523-7052

Publication date (Electronic): October 06 2017

Volume: 19

Issue: 19

Affiliations

[1 ] School of Chemical Engineering and Technology, Hebei University of Technology , Tianjin 300130, P. R. China.

[2 ] National-Local Joint Engineering Laboratory for Energy Conservation of Chemical Process Integration and Resources Utilization, Hebei University of Technology , Tianjin 300130, P. R. China.

Article

DOI: 10.1021/acs.orglett.7b02353

PubMed ID: 28901147

SO-VID: 54b7f697-10b3-46dc-a59e-1329f1206053

History

Data availability:

Comments

Comment on this article

scite_

Cited by 8

See all cited by