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      Nanoclays-containing bio-based packaging materials: properties, applications, safety, and regulatory issues

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          Abstract

          Food packaging is an important concept for consumer satisfaction and the increased shelf life of food products. The introduction of novel food packaging materials has become an emerging trend in recent years, which could be mainly due to environmental pollution caused by plastic packaging and to reduce food waste. Recently, numerous studies have been carried out on nanoclays or nanolayered silicate to be used in packaging material development as reinforcing filler composites. Different types of nanoclays have been used as food packaging materials, while montmorillonite (MMT), halloysite, bentonite (BT), Cloisite, and organically modified nanoclays have become of great interest. The incorporation of nanoclays into the packaging matrix improves the mechanical and barrier properties and at the same time prolongs the biodegradation of the packaging material. The purpose of this article is to examine the development of nanoclay-based food packaging materials. The review article highlights the current state of research on bio-based polymers with nanoclay for food packaging. In addition, the report analyses the mechanical, barrier, and antibacterial characteristics of nanoclay-based food packaging materials. Finally, it discusses the migration of nanoclays, toxicity levels, and the legislation associated with the application of nanoclays.

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          Overview of known plastic packaging-associated chemicals and their hazards

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            Bionanocomposites materials for food packaging applications: Concepts and future outlook

            Bionanocomposites materials open a chance for the usage of novel, high performance, lightweight, and ecofriendly composite materials making them take place the traditional non-biodegradable plastic packaging materials. Biopolymers like polysaccharides such as chitosan (CS), carboxymethyl cellulose (CMC), starch and cellophane could be used to resolve environmental hazards owing to their biodegradability and non-toxicity. In addition these advantages, polysaccharides have some disadvantages for example poor mechanical properties and low resistance to water. Therefore, nanomaterials are used to improve the thermal, mechanical and gas barrier properties without hindering their biodegradable and non-toxic characters. Furthermore, the most favorable nanomaterials are layered silicate nanoclays for example montmorillonite (MMT) and kaolinite, zinc oxide (ZnO-NPs), titanium dioxide (TiO2-NPs), and silver nanoparticles (Ag-NPs). In packaging application, the improvement of barrier properties of prepared films against oxygen, carbon dioxide, flavor compounds diffusion through the packaging films. Wide varieties of nanomaterials are suitable to offer smart and/or intelligent properties for food packaging materials, as demonstrated by oxygen scavenging capability, antimicrobial activity, and sign of the level of exposure to various harmful features for instance oxygen levels or insufficient temperatures. The compatibility between nanomaterials and polymers matrix consider the most challenge for the preparation of bionanocomposites as well as getting whole distribution of nanoparticles into the polymer matrix. We keen in this review the development of packaging materials performance and their mechanical, degradability and thermal stability as well as antibacterial activity for utilization of bionanocomposites in different packaging application is considered.
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              Reducing Postharvest Losses during Storage of Grain Crops to Strengthen Food Security in Developing Countries

              While fulfilling the food demand of an increasing population remains a major global concern, more than one-third of food is lost or wasted in postharvest operations. Reducing the postharvest losses, especially in developing countries, could be a sustainable solution to increase food availability, reduce pressure on natural resources, eliminate hunger and improve farmers’ livelihoods. Cereal grains are the basis of staple food in most of the developing nations, and account for the maximum postharvest losses on a calorific basis among all agricultural commodities. As much as 50%–60% cereal grains can be lost during the storage stage due only to the lack of technical inefficiency. Use of scientific storage methods can reduce these losses to as low as 1%–2%. This paper provides a comprehensive literature review of the grain postharvest losses in developing countries, the status and causes of storage losses and discusses the technological interventions to reduce these losses. The basics of hermetic storage, various technology options, and their effectiveness on several crops in different localities are discussed in detail.
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                Author and article information

                Contributors
                swarna.jaiswal@TUDublin.ie , swarna.jaiswal@outlook.com
                Journal
                J Nanostructure Chem
                J Nanostructure Chem
                Journal of Nanostructure in Chemistry
                Springer Berlin Heidelberg (Berlin/Heidelberg )
                2008-9244
                2193-8865
                2 February 2023
                2 February 2023
                : 1-23
                Affiliations
                [1 ]GRID grid.497880.a, School of Food Science and Environmental Health, College of Sciences and Health, , Technological University Dublin-City Campus, ; Central Quad, Grangegorman, Dublin, D07 ADY7 Ireland
                [2 ]GRID grid.497880.a, Environmental Sustainability and Health Institute, , Technological University Dublin-City Campus, ; Grangegorman, Dublin, D07 H6K8 Ireland
                Author information
                http://orcid.org/0000-0003-1414-9052
                Article
                525
                10.1007/s40097-023-00525-5
                9893189
                543d606f-df79-4950-8654-5994b9a9ce0a
                © The Author(s) 2023

                Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 21 May 2022
                : 10 January 2023
                : 12 January 2023
                Funding
                Funded by: Technological University Dublin
                Categories
                Review

                nanoclay,food packaging,mechanical properties,barrier properties,antimicrobial,biodegradation,migration,toxicity

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