Oryza sativa plant extract in 15% hydrochloric acid as a green corrosion inhibitor on the surface of stainless steel 410

Abstract

Fifteen percent hydrochloric acid (HCl) solutions are used for some cleaning processes in the petroleum industry. The use of such a corrosive medium is mainly responsible for the corrosion of the stainless steel (SS-410) vessels and pipings. In this study, the corrosion inhibiting properties of Oryza sativa plant extract (OSPE) from agricultural residues are investigated on SS-410 steel surfaces in a 15% HCl medium. Gravimetric analysis showed a maximum corrosion inhibition of 91.92% with 4 g/L OSPE in 15% HCl solution. Scanning electron microscopy (SEM), atomic force microscopy (AFM), and X-ray diffraction studies confirmed the adsorption of OSPE on the SS-410 surface. The adsorption of OSPE on SS-410 followed the Langmuir adsorption isotherm, indicating the formation of a monolayer on the SS-410 surface. The theoretical study confirmed that the anticorrosive effect could be mainly related to the phytochemical 9,12,15-octadecatrienoic acid 2,3-dihydroxypropyl ester. Consequently, the OSPE containing this phytochemical shows an anticorrosive behavior on the SS-410 surface in an acidic 15% HCl solution.