28
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: found
      Is Open Access

      Recent Progresses in Electrocatalysts for Water Electrolysis

      Read this article at

      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          Abstract

          The study of hydrogen evolution reaction and oxygen evolution reaction electrocatalysts for water electrolysis is a developing field in which noble metal-based materials are commonly used. However, the associated high cost and low abundance of noble metals limit their practical application. Non-noble metal catalysts, aside from being inexpensive, highly abundant and environmental friendly, can possess high electrical conductivity, good structural tunability and comparable electrocatalytic performances to state-of-the-art noble metals, particularly in alkaline media, making them desirable candidates to reduce or replace noble metals as promising electrocatalysts for water electrolysis. This article will review and provide an overview of the fundamental knowledge related to water electrolysis with a focus on the development and progress of non-noble metal-based electrocatalysts in alkaline, polymer exchange membrane and solid oxide electrolysis. A critical analysis of the various catalysts currently available is also provided with discussions on current challenges and future perspectives. In addition, to facilitate future research and development, several possible research directions to overcome these challenges are provided in this article.

          Graphical Abstract

          Related collections

          Most cited references365

          • Record: found
          • Abstract: found
          • Article: not found

          Design of electrocatalysts for oxygen- and hydrogen-involving energy conversion reactions.

          A fundamental change has been achieved in understanding surface electrochemistry due to the profound knowledge of the nature of electrocatalytic processes accumulated over the past several decades and to the recent technological advances in spectroscopy and high resolution imaging. Nowadays one can preferably design electrocatalysts based on the deep theoretical knowledge of electronic structures, via computer-guided engineering of the surface and (electro)chemical properties of materials, followed by the synthesis of practical materials with high performance for specific reactions. This review provides insights into both theoretical and experimental electrochemistry toward a better understanding of a series of key clean energy conversion reactions including oxygen reduction reaction (ORR), oxygen evolution reaction (OER), and hydrogen evolution reaction (HER). The emphasis of this review is on the origin of the electrocatalytic activity of nanostructured catalysts toward the aforementioned reactions by correlating the apparent electrode performance with their intrinsic electrochemical properties. Also, a rational design of electrocatalysts is proposed starting from the most fundamental aspects of the electronic structure engineering to a more practical level of nanotechnological fabrication.
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Nitrogen-doped carbon nanotube arrays with high electrocatalytic activity for oxygen reduction.

            The large-scale practical application of fuel cells will be difficult to realize if the expensive platinum-based electrocatalysts for oxygen reduction reactions (ORRs) cannot be replaced by other efficient, low-cost, and stable electrodes. Here, we report that vertically aligned nitrogen-containing carbon nanotubes (VA-NCNTs) can act as a metal-free electrode with a much better electrocatalytic activity, long-term operation stability, and tolerance to crossover effect than platinum for oxygen reduction in alkaline fuel cells. In air-saturated 0.1 molar potassium hydroxide, we observed a steady-state output potential of -80 millivolts and a current density of 4.1 milliamps per square centimeter at -0.22 volts, compared with -85 millivolts and 1.1 milliamps per square centimeter at -0.20 volts for a platinum-carbon electrode. The incorporation of electron-accepting nitrogen atoms in the conjugated nanotube carbon plane appears to impart a relatively high positive charge density on adjacent carbon atoms. This effect, coupled with aligning the NCNTs, provides a four-electron pathway for the ORR on VA-NCNTs with a superb performance.
              Bookmark
              • Record: found
              • Abstract: not found
              • Article: not found

              Universality in Oxygen Evolution Electrocatalysis on Oxide Surfaces

                Bookmark

                Author and article information

                Contributors
                Journal
                Electrochemical Energy Reviews
                Electrochem. Energ. Rev.
                Springer Science and Business Media LLC
                2520-8489
                2520-8136
                December 2018
                July 28 2018
                December 2018
                : 1
                : 4
                : 483-530
                Article
                10.1007/s41918-018-0014-z
                4e627646-f8a7-4efc-bb1c-74c9902e24b1
                © 2018

                https://creativecommons.org/licenses/by/4.0

                https://creativecommons.org/licenses/by/4.0

                History

                Comments

                Comment on this article

                scite_
                0
                0
                0
                0
                Smart Citations
                0
                0
                0
                0
                Citing PublicationsSupportingMentioningContrasting
                View Citations

                See how this article has been cited at scite.ai

                scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.

                Similar content396

                Cited by90

                Most referenced authors4,358