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      Ni Flower/MXene-Melamine Foam Derived 3D Magnetic/Conductive Networks for Ultra-Efficient Microwave Absorption and Infrared Stealth

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          Highlights

          • Ni-MXene/MF foam is synthesized via an electrostatic assembly and dip-coating process.

          • The “micro-capacitor” structure of Ni/MXene and the 3D porous structure of MF endow the foam excellent impedance matching and wave absorption performance.

          • The excellent heat insulation, infrared stealth, and flame-retardant performances are achieved.

          Supplementary Information

          The online version contains supplementary material available at 10.1007/s40820-022-00812-w.

          Abstract

          The development of multifunctional and efficient electromagnetic wave absorbing materials is a challenging research hotspot. Here, the magnetized Ni flower/MXene hybrids are successfully assembled on the surface of melamine foam (MF) through electrostatic self-assembly and dip-coating adsorption process, realizing the integration of microwave absorption, infrared stealth, and flame retardant. Remarkably, the Ni/MXene-MF achieves a minimum reflection loss (RL min) of − 62.7 dB with a corresponding effective absorption bandwidth (EAB) of 6.24 GHz at 2 mm and an EAB of 6.88 GHz at 1.8 mm. Strong electromagnetic wave absorption is attributed to the three-dimensional magnetic/conductive networks, which provided excellent impedance matching, dielectric loss, magnetic loss, interface polarization, and multiple attenuations. In addition, the Ni/MXene-MF endows low density, excellent heat insulation, infrared stealth, and flame-retardant functions. This work provided a new development strategy for the design of multifunctional and efficient electromagnetic wave absorbing materials.

          Supplementary Information

          The online version contains supplementary material available at 10.1007/s40820-022-00812-w.

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          Most cited references73

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          Guidelines for Synthesis and Processing of Two-Dimensional Titanium Carbide (Ti3C2Tx MXene)

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            CoNi@SiO2 @TiO2 and CoNi@Air@TiO2 Microspheres with Strong Wideband Microwave Absorption.

            The synthesis of CoNi@SiO2 @TiO2 core-shell and CoNi@Air@TiO2 yolk-shell microspheres is reported for the first time. Owing to the magnetic-dielectric synergistic effect, the obtained CoNi@SiO2 @TiO2 microspheres exhibit outstanding microwave absorption performance with a maximum reflection loss of -58.2 dB and wide bandwidth of 8.1 GHz (8.0-16.1 GHz, < -10 dB).
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              Broadband and tunable high-performance microwave absorption of an ultralight and highly compressible graphene foam.

              The broadband and tunable high-performance microwave absorption properties of an ultralight and highly compressible graphene foam (GF) are investigated. Simply via physical compression, the microwave absorption performance can be tuned. The qualified bandwidth coverage of 93.8% (60.5 GHz/64.5 GHz) is achieved for the GF under 90% compressive strain (1.0 mm thickness). This mainly because of the 3D conductive network.
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                Author and article information

                Contributors
                xianhu.liu@zzu.edu.cn
                Journal
                Nanomicro Lett
                Nanomicro Lett
                Nano-Micro Letters
                Springer Singapore (Singapore )
                2311-6706
                2150-5551
                21 February 2022
                21 February 2022
                December 2022
                : 14
                : 63
                Affiliations
                [1 ]GRID grid.207374.5, ISNI 0000 0001 2189 3846, Key Laboratory of Advanced Material Processing & Mold (Ministry of Education), National Engineering Research Center for Advanced Polymer Processing Technology, College of Materials Science and Engineering, , Zhengzhou University, ; Zhengzhou, 450002 People’s Republic of China
                [2 ]GRID grid.5330.5, ISNI 0000 0001 2107 3311, Institute of Polymer Materials, , Friedrich-Alexander-University Erlangen-Nuremberg, ; Martensstr. 7, 91058 Erlangen, Germany
                [3 ]GRID grid.411461.7, ISNI 0000 0001 2315 1184, Integrated Composites Laboratory (ICL), Department of Chemical & Biomolecular Engineering, , University of Tennessee, ; Knoxville, TN 37996 USA
                Article
                812
                10.1007/s40820-022-00812-w
                8861240
                35190917
                4bb0cea6-7255-4e90-9bba-b9df963be0a4
                © The Author(s) 2022

                Open AccessThis article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.

                History
                : 18 December 2021
                : 22 January 2022
                Funding
                Funded by: Shanghai Jiao Tong University
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                Article
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                © The Author(s) 2022

                ni-mxene/melamine foam,microwave absorption,heat insulation,infrared stealth,flame-retardant

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