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      Nanostructured Surface Finishing and Coatings: Functional Properties and Applications

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          Abstract

          This review presents current literature on different nanocomposite coatings and surface finishing for textiles, and in particular this study has focused on smart materials, drug-delivery systems, industrial, antifouling and nano/ultrafiltration membrane coatings. Each of these nanostructured coatings shows interesting properties for different fields of application. In this review, particular attention is paid to the synthesis and the consequent physico-chemical characteristics of each coating and, therefore, to the different parameters that influence the substrate deposition process. Several techniques used in the characterization of these surface finishing coatings were also described. In this review the sol–gel method for preparing stimuli-responsive coatings as smart sensor materials is described; polymers and nanoparticles sensitive to pH, temperature, phase, light and biomolecules are also treated; nanomaterials based on phosphorus, borates, hydroxy carbonates and silicones are used and described as flame-retardant coatings; organic/inorganic hybrid sol–gel coatings for industrial applications are illustrated; carbon nanotubes, metallic oxides and polymers are employed for nano/ultrafiltration membranes and antifouling coatings. Research institutes and industries have collaborated in the advancement of nanotechnology by optimizing conversion processes of conventional materials into coatings with new functionalities for intelligent applications.

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          Most cited references234

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          A review on polymer nanofibers by electrospinning and their applications in nanocomposites

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            Nanofiltration membranes review: Recent advances and future prospects

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              Enabling graphene oxide nanosheets as water separation membranes.

              We report a novel procedure to synthesize a new type of water separation membrane using graphene oxide (GO) nanosheets such that water can flow through the nanochannels between GO layers while unwanted solutes are rejected by size exclusion and charge effects. The GO membrane was made via layer-by-layer deposition of GO nanosheets, which were cross-linked by 1,3,5-benzenetricarbonyl trichloride, on a polydopamine-coated polysulfone support. The cross-linking not only provided the stacked GO nanosheets with the necessary stability to overcome their inherent dispensability in water environment but also fine-tuned the charges, functionality, and spacing of the GO nanosheets. We then tested the membranes synthesized with different numbers of GO layers to demonstrate their interesting water separation performance. It was found that the GO membrane flux ranged between 80 and 276 LMH/MPa, roughly 4-10 times higher than that of most commercial nanofiltration membranes. Although the GO membrane in the present development stage had a relatively low rejection (6-46%) of monovalent and divalent salts, it exhibited a moderate rejection (46-66%) of Methylene blue and a high rejection (93-95%) of Rhodamine-WT. We conclude the paper by emphasizing that the facile synthesis of a GO membrane exploiting the ideal properties of inexpensive GO materials offers a myriad of opportunities to modify its physicochemical properties, potentially making the GO membrane a next-generation, cost-effective, and sustainable alternative to the long-existing thin-film composite polyamide membranes for water separation applications.
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                Author and article information

                Contributors
                Role: Academic Editor
                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                22 May 2021
                June 2021
                : 14
                : 11
                : 2733
                Affiliations
                [1 ]Institute for the Study of Nanostructured Materials, ISMN–CNR, Palermo, c/o Department of ChiBioFarAm, University of Messina, Viale F. Stagno d’Alcontres 31, Vill. S. Agata, 98166 Messina, Italy; ileana.ielo@ 123456ismn.cnr.it (I.I.); fausta.giacobello@ 123456ismn.cnr.it (F.G.); ssfameni@ 123456unime.it (S.S.)
                [2 ]Department of Engineering, University of Messina, Contrada di Dio, S. Agata, 98166 Messina, Italy
                [3 ]Department of Chemical, Biological, Pharmaceutical and Analytical Sciences (ChiBioFarAm), University of Messina, Viale F. Stagno d’Alcontres 31, Vill. S. Agata, 98166 Messina, Italy; girando@ 123456unime.it (G.R.); mgalletta@ 123456unime.it (M.G.)
                [4 ]Department of Engineering and Applied Sciences, University of Bergamo, Viale Marconi 5, 24044 Dalmine (BG), Italy; valentina.trovato@ 123456unibg.it
                Author notes
                [* ]Correspondence: giuseppe.rosace@ 123456unibg.it (G.R.); mariarosaria.plutino@ 123456cnr.it (M.R.P.); Tel.: +39-035-205-2021 (G.R.); +39-090-676-5713 (M.R.P.)
                Author information
                https://orcid.org/0000-0002-6101-8015
                https://orcid.org/0000-0002-5148-1540
                https://orcid.org/0000-0002-6618-4311
                https://orcid.org/0000-0002-4459-5742
                https://orcid.org/0000-0003-0604-4453
                https://orcid.org/0000-0002-5980-2003
                Article
                materials-14-02733
                10.3390/ma14112733
                8196899
                34067241
                48b6ffbd-c5e5-4583-89d2-4808df65f2d2
                © 2021 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( https://creativecommons.org/licenses/by/4.0/).

                History
                : 20 April 2021
                : 19 May 2021
                Categories
                Review

                halochromic wearable sensors,drug delivery systems,flame retardant,industrial coatings,filtration membranes,antifouling coatings

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