In the title compound, [Co(CH 3CO 2)(C 18H 24N 6)]PF 6, the Co II atom is pentacoordinated in a distorted trigonal–bipyramidal geometry by four N atoms from a tripodal ligand and one O atom from a monodentate acetate ligand. The crystal packing is stabilized by intermolecular C—H⋯F and C—H⋯O hydrogen bonds.
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