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      Metal-insulator transition in quarter-filled Hubbard model on triangular lattice and its implication for the physics of \(Na_{0.5}CoO_{2}\)

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          Abstract

          The metal-insulator transition of the quarter-filled Hubbard model on triangular lattice is studied at the mean field level. We find a quasi-one dimensional metallic state with a collinear magnetic order competes closely with an insulating state with a non-coplanar magnetic order for both signs of the hopping integral \(t\). In the strong correlation regime(\(U/|t|\gg1\)), it is found that the metal-insulator transition of the system occurs in a two-step manner. The quasi-one dimensional metallic state with collinear magnetic order is found to be stable in an intermediate temperature region between the paramagnetic metallic phase and the non-coplanar insulating phase. Possible relevance of these results to the physics of metal-insulator transition in \(Na_{0.5}CoO_{2}\) is discussed.

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          Superconductivity in two-dimensional CoO2 layers.

          Since the discovery of high-transition-temperature (high-T(c)) superconductivity in layered copper oxides, many researchers have searched for similar behaviour in other layered metal oxides involving 3d-transition metals, such as cobalt and nickel. Such attempts have so far failed, with the result that the copper oxide layer is thought to be essential for superconductivity. Here we report that Na(x)CoO2*yH2O (x approximately 0.35, y approximately 1.3) is a superconductor with a T(c) of about 5 K. This compound consists of two-dimensional CoO2 layers separated by a thick insulating layer of Na+ ions and H2O molecules. There is a marked resemblance in superconducting properties between the present material and high-T(c) copper oxides, suggesting that the two systems have similar underlying physics.
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            Spin entropy as the likely source of enhanced thermopower in $\rm\bf Na_xCo_2O_4

            In an electric field, the flow of electrons in a solid produces an entropy current in addition to the familiar charge current. This Peltier effect underlies all thermoelectric refrigerators. The upsurge in thermoelectric cooling applications has led to a search for more efficient Peltier materials and to renewed theoretical interest in how electron-electron interaction may enhance the thermopower \(Q\) of materials such as the transition-metal oxides \cite{Mahan,Beni,Kotliar,Chaikin}. An important factor in this enhancement is the electronic spin entropy, which is predicted \cite{Chaikin,Kwak,KwakChaikin} to dominate the entropy current. Here we report evidence for such suppression in the layered oxide \(\rm Na_xCo_2O_4\), and present evidence that it is a strong-correlation effect.
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              Author and article information

              Journal
              2010-01-04
              Article
              1001.0620
              3f7dcafc-b6ba-4ea9-bef2-0babed07ce97

              http://arxiv.org/licenses/nonexclusive-distrib/1.0/

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              Custom metadata
              cond-mat.str-el

              Condensed matter
              Condensed matter

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