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      Nanomaterials Used in Conservation and Restoration of Cultural Heritage: An Up-to-Date Overview

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          Abstract

          In the last few years, the preservation of cultural heritage has become an important issue globally, due to the fact that artifacts and monuments are continually threatened by degradation. It is thus very important to find adequate consolidators that are capable of saving and maintaining the natural aspect of these objects. This study aims to provide an updated survey of the main nanomaterials used for the conservation and restoration of cultural heritage. In the last few years, besides the classic nanomaterials used in this field, such as metal nanoparticles (copper and silver) and metal oxides (zinc and aluminum), hydroxyapatite and carbonated derivatives, tubular nanomaterials (such as carbon nanotubes) have been used as a potential consolidate material of cultural heritage. Tubular nanomaterials have attracted attention for use in different fields due to their structures, as well as their ability to present multiple walls. These nanotubes have the necessary properties in preserving cultural heritage, such as superior mechanical and elastic strength (even higher than steel), high hydrophobicity (with a contact angle up to 140°), optical properties (high photodegradation protection), large specific surface area (from 50 to 1315 m 2/g, depending on the number of walls) for absorption of other nanomaterials and relatively good biocompatibility.

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          Characterization techniques for nanoparticles: comparison and complementarity upon studying nanoparticle properties

          Combined and carefully selected use of experimental techniques – understanding nanoparticle properties and optimizing performance in applications. Nanostructures have attracted huge interest as a rapidly growing class of materials for many applications. Several techniques have been used to characterize the size, crystal structure, elemental composition and a variety of other physical properties of nanoparticles. In several cases, there are physical properties that can be evaluated by more than one technique. Different strengths and limitations of each technique complicate the choice of the most suitable method, while often a combinatorial characterization approach is needed. In addition, given that the significance of nanoparticles in basic research and applications is constantly increasing, it is necessary that researchers from separate fields overcome the challenges in the reproducible and reliable characterization of nanomaterials, after their synthesis and further process ( e.g. annealing) stages. The principal objective of this review is to summarize the present knowledge on the use, advances, advantages and weaknesses of a large number of experimental techniques that are available for the characterization of nanoparticles. Different characterization techniques are classified according to the concept/group of the technique used, the information they can provide, or the materials that they are destined for. We describe the main characteristics of the techniques and their operation principles and we give various examples of their use, presenting them in a comparative mode, when possible, in relation to the property studied in each case.
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            Sonochemical synthesis of nanomaterials.

            High intensity ultrasound can be used for the production of novel materials and provides an unusual route to known materials without bulk high temperatures, high pressures, or long reaction times. Several phenomena are responsible for sonochemistry and specifically the production or modification of nanomaterials during ultrasonic irradiation. The most notable effects are consequences of acoustic cavitation (the formation, growth, and implosive collapse of bubbles), and can be categorized as primary sonochemistry (gas-phase chemistry occurring inside collapsing bubbles), secondary sonochemistry (solution-phase chemistry occurring outside the bubbles), and physical modifications (caused by high-speed jets or shock waves derived from bubble collapse). This tutorial review provides examples of how the chemical and physical effects of high intensity ultrasound can be exploited for the preparation or modification of a wide range of nanostructured materials.
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              Carbon nanotubes: properties, synthesis, purification, and medical applications

              Current discoveries of different forms of carbon nanostructures have motivated research on their applications in various fields. They hold promise for applications in medicine, gene, and drug delivery areas. Many different production methods for carbon nanotubes (CNTs) have been introduced; functionalization, filling, doping, and chemical modification have been achieved, and characterization, separation, and manipulation of individual CNTs are now possible. Parameters such as structure, surface area, surface charge, size distribution, surface chemistry, and agglomeration state as well as purity of the samples have considerable impact on the reactivity of carbon nanotubes. Otherwise, the strength and flexibility of carbon nanotubes make them of potential use in controlling other nanoscale structures, which suggests they will have a significant role in nanotechnology engineering.
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                Author and article information

                Journal
                Materials (Basel)
                Materials (Basel)
                materials
                Materials
                MDPI
                1996-1944
                29 April 2020
                May 2020
                : 13
                : 9
                : 2064
                Affiliations
                [1 ]“Evaluation and Conservation of Cultural Heritage” Research Group, National Institute for Research and Development in Chemistry and Petrochemistry–ICECHIM, 060021 Bucharest, Romania; madalina.e.david@ 123456gmail.com (M.E.D.); rmgrigorescu@ 123456gmail.com (R.M.G.); lorenna77ro@ 123456yahoo.com (L.I.); andreiramona@ 123456hotmail.com (E.R.A.)
                [2 ]Doctoral School of Materials Engineering Department, Valahia University, 130104 Targoviste, Romania
                Author notes
                [* ]Correspondence: rodica_ion2000@ 123456yahoo.co.uk ; Tel.: +40-21-316-3094
                Author information
                https://orcid.org/0000-0002-1550-4661
                https://orcid.org/0000-0002-9842-3321
                https://orcid.org/0000-0002-4839-5983
                Article
                materials-13-02064
                10.3390/ma13092064
                7254209
                32365734
                399a6a52-affb-4c8c-86e1-851cbeda7fc6
                © 2020 by the authors.

                Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license ( http://creativecommons.org/licenses/by/4.0/).

                History
                : 02 April 2020
                : 27 April 2020
                Categories
                Review

                carbon nanotubes,nanomaterials,metal nanoparticles,hydroxyapatites,cultural heritage,carbonated hydroxyapatite

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