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      Polypyrrole micro/nanostructures and their soft materials in versatile forms: construction and applications

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          Abstract

          Key issues regarding the syntheses of polypyrrole nanomaterials and their recent application were discussed. Polypyrrole derived dispersions, hydrogels, membranes and composites were outlined by considering improved conductivity and processability.

          Abstract

          With the increasing research interest in the fields of advanced materials, energy conservation and environmental protection, polypyrrole (PPy), a widely studied conducting polymer, has shown great promise in a lot of applications. The synthetic conditions and morphology control of PPy simultaneously affect its conductivity and processability and eventually determine the application behaviour. This review goes through the preparation of PPy nanostructures, which have been popular in the last two decades, and PPy-based soft materials, which have been of great concern in recent years. The key issues for controlling PPy morphology, increasing conductivity, and improving processability are discussed. Aiming at application in flexible electronics, energy storage, solar energy utilization and contamination separation, a brief but comprehensive summary of the construction of PPy-based soft materials and their performance is presented. With this content, this review will provide a systematic development of PPy in an easily handled state and therefore expand its use in newly emerging application fields.

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          Most cited references134

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          Nanostructured conductive polypyrrole hydrogels as high-performance, flexible supercapacitor electrodes

          A spongy polypyrrole based conductive hydrogel with chemically tunable structures and electrochemical characteristics was developed for highly flexible solid-state supercapacitors. Electrochemically active conducting polymers are an important class of materials for applications in energy storage devices such as batteries and supercapacitors, owing to their advantageous features of unique three-dimensional (3D) porous microstructure, high capacitive energy density, scalable synthesis and light weight. Here, we synthesized a nanostructured conductive polypyrrole (PPy) hydrogel via an interfacial polymerization method. The simple synthesis chemistry offers the conductive hydrogel tunable nanostructures and electrochemical performance, as well as scalable processability. Moreover, the unique 3D porous nanostructure constructed by interconnected polymer nanospheres endows PPy hydrogels with good mechanical properties and high performance acting as supercapacitor electrodes with a specific capacitance of ∼380 F g −1 , excellent rate capability, and areal capacitance as high as ∼6.4 F cm −2 at a mass loading of 20 mg cm −2 .
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            Multilayer Polypyrrole Nanosheets with Self‐Organized Surface Structures for Flexible and Efficient Solar–Thermal Energy Conversion

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              Nanostructured Polypyrrole as a flexible electrode material of supercapacitor

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                Author and article information

                Contributors
                Journal
                MCFAC5
                Materials Chemistry Frontiers
                Mater. Chem. Front.
                Royal Society of Chemistry (RSC)
                2052-1537
                January 15 2024
                2024
                : 8
                : 2
                : 434-454
                Affiliations
                [1 ]School of Chemistry, Xi’an Jiaotong University, Engineering Research Center of Energy Storage Materials and Devices, Ministry of Education, Xi’an, 710049, Shaanxi, China
                [2 ]Jiangsu Polymet Technology Co., Ltd, Zhenjiang, 212000, Jiangsu, China
                Article
                10.1039/D3QM00826F
                366cd64b-b2cd-4f50-9946-0cdfff5141f7
                © 2024

                http://rsc.li/journals-terms-of-use

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