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      Recent advancement of biomass-derived porous carbon based materials for energy and environmental remediation applications

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          Abstract

          The review summarizes the most recent advances, challenges and future perspectives in biomass/waste-derived nanoporous carbon materials for energy and environmental remediation applications.

          Abstract

          In recent times, increasing environmental pollution alongside depletion of fossil fuel reserves has led to a rejuvenated interest in utilizing biomass and waste materials. Advanced porous carbons derived from such abundantly available and carbon rich feedstock precursors have been extensively used for clean energy storage and environmental remediation applications. This is credited to the exclusive properties like high specific surface area with tunable pore size, developed pore architecture and chemical stability. Simultaneously, several techniques have been progressively designed and upgraded for pollutant abatement in terms of economical and facile methodologies. The review aims to highlight the importance of biomass/waste-derived nanoporous carbon materials for energy and environmental applications. Various bio-synthetic activation methods and up to date research activities in the design and sustainable development of such state-of-the-art materials have been introduced. In addition, promising applications of nanoporous carbons in electrochemical systems and for environmental protection are briefly reviewed. Finally, current challenges and strategies for future research are summarized. It is expected that this review paper would assist the reader to acquire concise and systematic information as well as contribute novel ideas over a wide spectrum of disciplines.

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          The biomass distribution on Earth

          Significance The composition of the biosphere is a fundamental question in biology, yet a global quantitative account of the biomass of each taxon is still lacking. We assemble a census of the biomass of all kingdoms of life. This analysis provides a holistic view of the composition of the biosphere and allows us to observe broad patterns over taxonomic categories, geographic locations, and trophic modes.
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            Is Open Access

            Biochar physicochemical properties: pyrolysis temperature and feedstock kind effects

            Biochar is a pyrogenous, organic material synthesized through pyrolysis of different biomass (plant or animal waste). The potential biochar applications include: (1) pollution remediation due to high CEC and specific surface area; (2) soil fertility improvement on the way of liming effect, enrichment in volatile matter and increase of pore volume, (3) carbon sequestration due to carbon and ash content, etc. Biochar properties are affected by several technological parameters, mainly pyrolysis temperature and feedstock kind, which differentiation can lead to products with a wide range of values of pH, specific surface area, pore volume, CEC, volatile matter, ash and carbon content. High pyrolysis temperature promotes the production of biochar with a strongly developed specific surface area, high porosity, pH as well as content of ash and carbon, but with low values of CEC and content of volatile matter. This is most likely due to significant degree of organic matter decomposition. Biochars produced from animal litter and solid waste feedstocks exhibit lower surface areas, carbon content, volatile matter and high CEC compared to biochars produced from crop residue and wood biomass, even at higher pyrolysis temperatures. The reason for this difference is considerable variation in lignin and cellulose content as well as in moisture content of biomass. The physicochemical properties of biochar determine application of this biomaterial as an additive to improve soil quality. This review succinctly presents the impact of pyrolysis temperature and the type of biomass on the physicochemical characteristics of biochar and its impact on soil fertility.
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              Mesoporous Carbon Materials: Synthesis and Modification

              Porous carbon materials are of interest in many applications because of their high surface area and physicochemical properties. Conventional syntheses can only produce randomly porous materials, with little control over the pore-size distributions, let alone mesostructures. Recent breakthroughs in the preparation of other porous materials have resulted in the development of methods for the preparation of mesoporous carbon materials with extremely high surface areas and ordered mesostructures, with potential applications as catalysts, separation media, and advanced electronic materials in many scientific disciplines. Current syntheses can be categorized as either hard-template or soft-template methods. Both are examined in this Review along with procedures for surface functionalization of the carbon materials obtained.
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                Author and article information

                Contributors
                (View ORCID Profile)
                Journal
                JMCAET
                Journal of Materials Chemistry A
                J. Mater. Chem. A
                Royal Society of Chemistry (RSC)
                2050-7488
                2050-7496
                March 30 2022
                2022
                : 10
                : 13
                : 6965-7005
                Affiliations
                [1 ]Department of Chemistry, National Institute of Technology Meghalaya, Shillong, 793003, Meghalaya, India
                [2 ]Department of Physics, School of Advanced Sciences, Vellore Institute of Technology, Vellore, 632014, Tamil Nadu, India
                [3 ]Department of Chemistry, National Institute of Technology Warangal, Warangal, 506004, Telangana, India
                Article
                10.1039/D1TA10269A
                36000287
                350a7452-5023-45b2-bbe5-6d4dc14d05ab
                © 2022

                http://rsc.li/journals-terms-of-use

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