56
views
0
recommends
+1 Recommend
0 collections
    0
    shares
      • Record: found
      • Abstract: found
      • Article: found
      Is Open Access

      Application of U/Th and 40Ar/ 39Ar Dating to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic Site in Ardèche, France

      research-article

      Read this article at

      Bookmark
          There is no author summary for this article yet. Authors can add summaries to their articles on ScienceOpen to make them more accessible to a non-specialist audience.

          Abstract

          Refined radio-isotopic dating techniques have been applied to Orgnac 3, a Late Acheulean and Early Middle Palaeolithic site in France. Evidence of Levallois core technology appeared in level 4b in the middle of the sequence, became predominant in the upper horizons, and was best represented in uppermost level 1, making the site one of the oldest examples of Levallois technology. In our dating study, fourteen speleothem samples from levels 7, 6 and 5b, were U/Th-dated. Four pure calcite samples from the speleothem PL1 (levels 5b, 6) yield ages between 265 ± 4 (PL1-3) and 312 ± 15 (PL1-6) thousand years ago (ka). Three samples from the top of a second stalagmite, PL2, yield dates ranging from 288 ± 10 ka (PL2-1) to 298 ± 17 ka (PL2-3). Three samples from the base of PL2 (level 7) yield much younger U/Th dates between 267 and 283 ka. These dates show that the speleothems PL1 and PL2 are contemporaneous and formed during marine isotope stage (MIS) 9 and MIS 8. Volcanic minerals in level 2, the upper sequence, were dated by the 40Ar/ 39Ar method, giving a weighted mean of 302.9 ± 2.5 ka (2σ) and an inverse isochron age of 302.9 ± 5.9 ka (2σ). Both 40Ar/ 39Ar dating of volcanic sanidines and U/Th dating of relatively pure and dense cave calcites are known to be well established. The first parallel application of the two geochronometers to Orgnac 3 yields generally consistent results, which point to the reliability of the two methods. The difference between their age results is discussed.

          Related collections

          Most cited references2

          • Record: found
          • Abstract: found
          • Article: not found

          Synchronizing rock clocks of Earth history.

          Calibration of the geological time scale is achieved by independent radioisotopic and astronomical dating, but these techniques yield discrepancies of approximately 1.0% or more, limiting our ability to reconstruct Earth history. To overcome this fundamental setback, we compared astronomical and 40Ar/39Ar ages of tephras in marine deposits in Morocco to calibrate the age of Fish Canyon sanidine, the most widely used standard in 40Ar/39Ar geochronology. This calibration results in a more precise older age of 28.201 +/- 0.046 million years ago (Ma) and reduces the 40Ar/39Ar method's absolute uncertainty from approximately 2.5 to 0.25%. In addition, this calibration provides tight constraints for the astronomical tuning of pre-Neogene successions, resulting in a mutually consistent age of approximately 65.95 Ma for the Cretaceous/Tertiary boundary.
            Bookmark
            • Record: found
            • Abstract: found
            • Article: not found

            Measurement of attogram quantities of 231Pa in dissolved and particulate fractions of seawater by isotope dilution thermal ionization mass spectroscopy.

            A technique has been developed to quantify ultratrace 231Pa (50-2000 ag; 1 ag = 10(-18) g) concentrations in seawater using isotope-dilution thermal ionization mass spectrometry (TIMS). The method is a modification of a process developed by Pickett et al. (Pickett, D. A.; Murrell, M. T.; Williams, R. W. Anal. Chem. 1994, 66, 1044-1049) and extends the technique to very low levels of protactinium. The procedural blank is 16 +/- 15 ag (2sigma), and the ionization efficiency (ions generated/atom loaded) approaches 0.5%. Measurement time is <1 h. The amount of 231Pa needed to produce 231Pa data with an uncertainty of +/-4-12% is 100-1000 ag (approximately 3 x 10(5) to 3 x 10(6) atoms). Replicate measurements made on known standards and seawater samples demonstrate that the analytical precision approximates that expected from counting statistics and that, based on detection limits of 38 and 49 ag, protactinium can be detected in a minimum sample size of surface seawater of approximately 2 L for suspended particulate matter and <0.1 L for filtered (<0.4 microm) seawater, respectively. The concentration of 231Pa (tens of attograms per liter) can be determined with an uncertainty of +/-5-10% (2sigma) for suspended particulate matter filtered from 5 to 10 L of seawater. For the dissolved fraction, 0.5-1 L of seawater yields 231Pa measurements with a precision of 1-10%. Sample size requirements are orders of magnitude less than traditional decay-counting techniques and significantly less than previously reported ICP-MS techniques. Our technique can also be applied to other environmental samples, including cave waters, rivers, and igneous rocks.
              Bookmark

              Author and article information

              Contributors
              Role: Editor
              Journal
              PLoS One
              PLoS ONE
              plos
              plosone
              PLoS ONE
              Public Library of Science (San Francisco, USA )
              1932-6203
              2013
              5 December 2013
              : 8
              : 12
              : e82394
              Affiliations
              [1 ]Université Nice Sophia Antipolis, Campus Saint-Jean-d'Angély, SJA3 - CEPAM- UMR 7264 CNRS, Nice Cedex 4, France
              [2 ]Géoazur, UMR7329, UNS-CNRS-IRD-OCA, Valbonne, France
              [3 ]College of Geographical Sciences, Nanjing Normal University, Nanjing, China
              [4 ]High-precision Mass Spectrometry and Environment Change Laboratory (HISPEC), Department of Geoscience, National Taiwan University N°1, Taipei, Taiwan ROC
              [5 ]Département de Préhistoire, UMR 7194, MNHN, IPH, Paris, France
              [6 ]CNRS, Macon, France
              [7 ]Laboratoire Départemental de Préhistoire du Lazaret, Nice, France
              [8 ]Université Nice Sophia Antipolis, Département Terre-Environnement-Espace, Parc Valrose, Nice Cedex 2, France
              University of Oxford, United Kingdom
              Author notes

              Competing Interests: The authors have declared that no competing interests exist.

              Conceived and designed the experiments: VM GS CCS CV. Performed the experiments: VM GS CCS CCW. Analyzed the data: VM GS CCS CCW CV SG. Contributed reagents/materials/analysis tools: VM MM. Wrote the manuscript: VM GS CCS CV MHM. Sampling: VM JC SK MM.

              Article
              PONE-D-13-26717
              10.1371/journal.pone.0082394
              3857827
              345af51c-fd27-4df3-8494-291d8bc6771f
              Copyright @ 2013

              This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

              History
              : 27 June 2013
              : 22 October 2013
              Funding
              U/Th isotopic measurements and dating were supported by Taiwan ROC NSC and NTU grants (101-2923-M-002-008-MY2, 101-2116-M-002-009, and 101R7625 to CCS). The funders had no role in study design, data collection and analysis, decision to publish, or preparation of the manuscript.
              Categories
              Research Article

              Uncategorized
              Uncategorized

              Comments

              Comment on this article