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      Effect of Pressure on Burning and Soot Characteristics of RP-3 Kerosene Droplets under Sub-Atmospheric Pressure

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          Abstract

          The burning and soot characteristics of RP-3 kerosene droplets under sub-atmospheric pressure were experimentally investigated in a pressure chamber. The droplet size during combustion was continuously recorded using a high-speed camera, and the burning rate based on the d 2–law was determined. The flame temperature was calculated from ICCD camera spectral data using two-color pyrometry, and the carbon soot volume fraction was measured by the calibrated laser-induced incandescence (LII) technique. Soot particles were also sampled using a thermophoretic deposition probe and characterized using a transmission electron microscope (TEM) for particle size and morphology. The results showed that the droplet burning rate increased monotonically with increasing pressure under sub-atmospheric pressure, and the flame temperature slightly decreased with increasing pressure. Sub-atmospheric pressure environment significantly inhibits the formation of soot particle clusters during the ignition of droplets. The average soot volume fraction in the flame increases approximately with increasing pressure at 0.2–1.0 bar with a power of 2.044 ± 0.066. As the pressure decreases from 1.0 to 0.2 bar, the average soot volume fraction decreases significantly from 11.801 to 0.437 ppm. This is mainly due to the fact that the sub-atmospheric environment not only inhibits the collision growth of soot particles but also promotes the oxidation process of soot particles. The collected soot particles reveal a significant reduction in particle size under sub-atmospheric pressure with average primary soot particles of 48.23, 40.06, 27.096, and 18.718 nm at 1.0, 0.6, 0.4, and 0.3 bar pressures, respectively. The change in the number density of carbon soot particles is not significant, which reveals that the change in the diameter of soot particles under sub-atmospheric pressure plays a key role in the change in the volume fraction of soot.

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          Soot formation

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            Recent advances in droplet vaporization and combustion

            C.K. Law (1982)
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              Laser-induced incandescence: recent trends and current questions

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                Author and article information

                Journal
                ACS Omega
                ACS Omega
                ao
                acsodf
                ACS Omega
                American Chemical Society
                2470-1343
                06 April 2023
                18 April 2023
                : 8
                : 15
                : 14053-14065
                Affiliations
                []State Key Laboratory of Clean Energy Utilization, Zhejiang University , Hangzhou 310027, China
                []Shanghai Institute of Space Propulsion , Shanghai 201112, China
                [§ ]Key Laboratory of Clean Energy and Carbon Neutrality of Zhejiang Province , Hangzhou 310027, China
                Author notes
                Author information
                https://orcid.org/0000-0002-7037-9007
                https://orcid.org/0000-0002-7521-2900
                Article
                10.1021/acsomega.3c00655
                10116641
                2ceee89e-cca2-461b-a3cb-f888f1a80a1e
                © 2023 The Authors. Published by American Chemical Society

                Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works ( https://creativecommons.org/licenses/by-nc-nd/4.0/).

                History
                : 01 February 2023
                : 28 March 2023
                Funding
                Funded by: National Natural Science Foundation of China, doi 10.13039/501100001809;
                Award ID: 52125605
                Funded by: Central University Basic Research Fund of China, doi 10.13039/501100018594;
                Award ID: 2022ZFJH004
                Funded by: Natural Science Foundation of Zhejiang Province, doi 10.13039/501100004731;
                Award ID: LZ21E06003
                Categories
                Article
                Custom metadata
                ao3c00655
                ao3c00655

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