6-[(2-Methyl­phen­yl)sulfan­yl]-5-propyl­pyrimidine-2,4(1 H,3 H)-dione

Abstract

In the title pyrimidine-2,4-dione derivative, C ₁₄H ₁₆N ₂O ₂S, the dihedral angle between the six-membered rings is 77.81 (10)°. The mol­ecule is twisted about the C _p—S (p = pyrimidine) bond, with a C—S—C—N torsion angle of −59.01 (17)°. An intramolecular C—H⋯S hydrogen bond generates an S(5) ring motif. In the crystal, bifurcated acceptor N—H⋯O and C—H⋯O hydrogen bonds generate inversion-related dimers incorporating R ₂ ¹(9) and R ₂ ²(8) loops. These dimers are connected into a chain extending along the a-axis direction by a second pair of inversion-related N—H⋯O hydrogen bonds, forming another R ₂ ²(8) loop. The crystal structure is further stabilized by weak inter­molecular C—H⋯π inter­actions, generating a three-dimensional network.