Process Water Recirculation during Hydrothermal Carbonization of Waste Biomass: Current Knowledge and Challenges

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Abstract

Hydrothermal carbonization (HTC) is considered as an efficient and constantly expanding eco-friendly methodology for thermochemical processing of high moisture waste biomass into solid biofuels and valuable carbonaceous materials. However, during HTC, a considerable amount of organics, initially present in the feedstock, are found in the process water (PW). PW recirculation is attracting an increasing interest in the hydrothermal process field as it offers the potential to increase the carbon recovery yield while increasing hydrochar energy density. PW recirculation can be considered as a viable method for the valorization and reuse of the HTC aqueous phase, both by reducing the amount of additional water used for the process and maximizing energy recovery from the HTC liquid residual fraction. In this work, the effects of PW recirculation, for different starting waste biomasses, on the properties of hydrochars and liquid phase products are reviewed. The mechanism of production and evolution of hydrochar during recirculation steps are discussed, highlighting the possible pathways which could enhance energy and carbon recovery. Challenges of PW recirculation are presented and research opportunities proposed, showing how PW recirculation could increase the economic viability of the process while contributing in mitigating environmental impacts.

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Energy production from biomass (Part 1): Overview of biomass.

Peter McKendry (2002)

The use of renewable energy sources is becoming increasingly necessary, if we are to achieve the changes required to address the impacts of global warming. Biomass is the most common form of renewable energy, widely used in the third world but until recently, less so in the Western world. Latterly much attention has been focused on identifying suitable biomass species, which can provide high-energy outputs, to replace conventional fossil fuel energy sources. The type of biomass required is largely determined by the energy conversion process and the form in which the energy is required. In the first of three papers, the background to biomass production (in a European climate) and plant properties is examined. In the second paper, energy conversion technologies are reviewed, with emphasis on the production of a gaseous fuel to supplement the gas derived from the landfilling of organic wastes (landfill gas) and used in gas engines to generate electricity. The potential of a restored landfill site to act as a biomass source, providing fuel to supplement landfill gas-fuelled power stations, is examined, together with a comparison of the economics of power production from purpose-grown biomass versus waste-biomass. The third paper considers particular gasification technologies and their potential for biomass gasification.